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Strategies Towards Novel Supercapacitor Electrodes

机译:新型超级电容器电极的策略

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摘要

Supercapacitors, also known as ultracapacitors or electrochemical capacitors, are receiving massive attention due to their potential for high power applications and due to their long cycle life characteristics. The charge storage of electrochemical capacitors is based either on electrolytic double layer capacitance and/or pseudocapacitance. For Supercapacitors relying on charge storage in the double layer at the interface of electrode surface and electrolyte, large surface area (≥ 1000 m~2 g~(-1)) carbon materials are very suitable, in particular as carbon powders such as carbon blacks are comparatively inexpensive. When using fine particulate carbon black as electrode material, typically a relatively high amount of a polymer binder is necessary in order to achieve good mechanical integrity within the electrode and good adherence to the current collector. However, the coverage of carbon particles with electronically insulating binder material increases the resistance of the electrode and furthermore may also obstruct the formation of the electrolytic double layer, hence may lower the capacitance. Our objective is to provide a method for the fabrication of supercapacitor electrodes without using additional binder by application. We performed carbon precipitation on a current collector substrate by a technique, which has been developed in our laboratory: substrate induced coagulation (SIC).
机译:超级电容器,也称为超级电容器或电化学电容器,由于其在高功率应用中的潜力和长循环寿命特性而受到了广泛的关注。电化学电容器的电荷存储基于电解双层电容和/或伪电容。对于依赖于电极表面和电解质界面的双层中电荷存储的超级电容器,非常适合使用大表面积(≥1000 m〜2 g〜(-1))的碳材料,特别是碳粉(例如炭黑)比较便宜。当使用细粒状炭黑作为电极材料时,通常需要相对大量的聚合物粘合剂,以实现电极内的良好机械完整性和对集流体的良好粘附。然而,用电绝缘粘合剂材料覆盖碳颗粒增加了电极的电阻,并且还可能阻碍电解双层的形成,因此可能降低电容。我们的目标是提供一种无需使用额外粘合剂即可制造超级电容器电极的方法。我们通过一种在实验室中开发的技术在集电器基板上进行了碳沉淀:基板诱导凝结(SIC)。

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