Synthesis and study of new clathrochelates from 1-phenyl-2(1'-plperidinyl) ethanone oxime ligand

机译：1-苯基-2（1'-哌啶基）乙酮肟配体的合成新型笼形螯合物的研究

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The paper studies the reactions of [ML(L-H)]X (where M = Ni, Cu and L = 1-phenyl-2(1'-piperidinyl) ethanone oxime) with Lewis acids like SnCl_4 and TiCl_4 when semiclathrochelates of [M(L-H)_2MCl_2]~(2+) type (M' = Ti, Sn) have been obtained. The complexes have been characterized by conductivity measurements, electronic and FT-IR spectra. Such complexes should be potential oxygen molecular carriers.

机译：本文研究了[ML（LH）] X（其中M = Ni，Cu和L = 1-苯基-2（1'-哌啶基）乙酮肟）与路易斯酸如SnCl_4和TiCl_4在[M（已获得LH）_2MCl_2]〜（2+）型（M'= Ti，Sn）。通过电导率测量，电子和FT-IR光谱对复合物进行了表征。这样的络合物应该是潜在的氧分子载体。

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来源
《12th Romanian International Conference on Chemistry and Chemical Engineering, Sep 13-15, 2001, Bucharest, Romania》|2001年|p.428-432|共5页
会议地点 Bucharest(RO);Bucharest(RO)
作者
M.D. Stanescu; I. Jitaru; O. Oprea; D. Alexandru;
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作者单位

"Aurel Vlaicu" University, Bd. Revolutiei, 81, 2900 Arad, ROMANIA;

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会议组织
原文格式 PDF
正文语种 eng
中图分类化学工业;
关键词
oximato metal complexes; clatrochelates; lewis acids; oxygen molecular carriers;

机译：肟金属配合物； clatrochelates;路易斯酸；氧分子载体;

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Synthesis and study of new clathrochelates from 1-phenyl-2(1'-plperidinyl) ethanone oxime ligand

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