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Modification of Donor/Acceptor Interface for Efficient Charge Transfer in Organic Solar Cells

机译:修改供体/受体界面以在有机太阳能电池中进行有效的电荷转移

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@@ Organic Solar Cells (OSCs) have various advantages such as low fabrication cost, lightweight, and high flexibility, compared with inorganic solar cells. Poly(3-hexylthiophene) (P3HT) is the most studied conjugated polymers as an electron donor, and [6,6]-phenyl-C61 butyric acid methyl ester (PCBM) is known as an excellent acceptor.1 The concept of bulk heterojunction (BHJ), I.e. A simple mixture of a donor and an acceptor in the films, was a major breakthrough for the improvement of the performance. Although relatively high performances have been reported, there is almost no information about the molecular structures at the interface of the donor and the acceptor in BHJ. Because important photophysical processes of OSCs such as charge transfer and recombination occur only at the interfaces, the understanding and the control of theinterfacial structuresare very important to improve the efficiency of OSCs.
机译:与无机太阳能电池相比,有机太阳能电池(OSC)具有各种优势,例如制造成本低,重量轻和灵活性高。聚(3-己基噻吩)(P3HT)是研究最多的共轭聚合物,是一种电子供体,而[6,6]-苯基-C61丁酸甲酯(PCBM)被称为出色的受体。1本体异质结的概念(BHJ),即薄膜中供体和受体的简单混合是改善性能的重大突破。尽管已经报道了相对较高的性能,但是在BHJ中几乎没有关于供体和受体界面处分子结构的信息。由于OSC的重要光物理过程(例如电荷转移和重组)仅发生在界面上,因此对界面结构的理解和控制对于提高OSC的效率非常重要。

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