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首页> 外文会议>18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会） >Optical Resolution of Racemic 2-Amio-1-Butanol with a Mushroom,Hypsizygus Marmoreus,to give (+)-2-Amio-1-Butanol and with another Mushroom,Flammulina Velutiper,to give (-)-2-Amio-1-Butanol
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Optical Resolution of Racemic 2-Amio-1-Butanol with a Mushroom,Hypsizygus Marmoreus,to give (+)-2-Amio-1-Butanol and with another Mushroom,Flammulina Velutiper,to give (-)-2-Amio-1-Butanol

机译：用蘑菇Hypsizygus Marmoreus消旋外消旋2-Amio-1-丁醇的光学拆分，得到（+）-2-Amio-1-丁醇，和另一个蘑菇，Flammulina Velutiper，得到（-）-2-Amio-1 -丁醇

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It has been reported that crystalline form racemates can be resoluted by various methods, but for optical resolution of liguid form racemates such as racemic alcohols, the method is limited in chromatograph. However, chiral compounds cannot be obtained on large scale by such method, so the chiral alcohols are very expensive. In our previous papers, bio-polymer materials, wool [1,2], casein [3-4] and mushroom [5] have been found to be able to use as optical resolution materials for some racemic alcohols to give corresponding optical alcohols. Recently, it has been found that in the optical resolution of racemic 2-amino-l-butanol, when a mushroom, hypsizygus marmoreus (H M), was used as a resolution material, (+)-2-amino-l-butanol could be obtained, and another mushroom, flammulina velutiper (F V), was used as a resolution material, (-)-2-amino-1-butanol could be obtained.
机译：据报道，晶状外消旋体可以通过各种方法进行固溶，但是对于光学形式的液体状外消旋体如外消旋醇的光学拆分，该方法在色谱仪中受到限制。但是，通过这种方法不能大规模获得手性化合物，因此手性醇非常昂贵。在我们以前的论文中，已经发现生物聚合物材料羊毛[1,2]，酪蛋白[3-4]和蘑菇[5]可以用作某些消旋醇的光学拆分材料，从而得到相应的光学醇。最近，已经发现，在外消旋2-氨基-1-丁醇的光学拆分中，当使用蘑菇（hypsizygus marmoreus，HM）作为拆分材料时，（+）-2-氨基-1-丁醇可以获得，然后使用另一种蘑菇，弗拉穆利（Vulmulina velutiper）（FV）作为拆分材料，可以获得（-）-2-氨基-1-丁醇。

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