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Polymeric Membrane Sensors Based on Mnomethoxypoly(ethylene glycol)-grafted-Chitosan (mPEG-g-CS) Film Electrode For Elective Iodide Determination

机译:基于甲氧基聚(乙二醇)接枝壳聚糖(mPEG-g-CS)薄膜电极的聚合物膜传感器用于碘化物的测定

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1.Introduction Numerous analytical methods have been reported for its determination at low concentration levels. Potentiometric sensors offer an inexpensive and convenientmethod for fast analysis with high sensitivity and selectivity.Ion elective electrodes have emerged as one of the most promising tools for direct determination of various species.In view of such advantages,efforts have been made to make selective sensors for different anions.However,most of these efforts have not been very fruitful.The developed sensors posses narrow working concentration range and suffer serious interference from anions just like SCN-,CN-,CkO4-. In order to have selective sensor for iodide, the most important requirement is to have an ionophore in the sensor which show high affinity towards iodide ion and poor for other anions. Recently, Mnomethoxypoly(ethylene glycol)-grafied-Chitosan (mPEG-g-CS) have also been explored as ionophores in the construction of ion-selective electrodes for iodide.
机译:1.引言据报道,有许多分析方法可用于低浓度测定。电位传感器为快速分析提供了一种廉价且便捷的方法,具有高灵敏度和选择性。离子选择电极已成为直接测定各种物种的最有希望的工具之一。鉴于此类优势,人们已在努力开发用于选择性分析的选择性传感器。不同的阴离子。然而,大多数这些努力并未取得丰硕的成果。发达的传感器具有狭窄的工作浓度范围,并且受到SCN-,CN-,CkO4-等阴离子的严重干扰。为了具有碘化物的选择性传感器,最重要的要求是在传感器中具有对碘化物离子具有高亲和力而对其他阴离子较弱的离子载体。近来,也已探索了甲氧基聚(乙二醇)接枝的壳聚糖(mPEG-g-CS)作为离子载体,用于构建碘化物的离子选择电极。

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