Rh(I)OR as Finely Tunable Base Catalyst

机译：Rh（I）OR作为精细可调的基础催化剂

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1.Introduction The Bronsted and Lewis bases are one of the benchmark reagents in organic synthesis.We here focused on a finely tunable base catalyst based on transition metal center with various types of ligands.This presentation opens a basic nature of Rh(I)OR complex with suitable ligand.The representative outcome of Rh(I)OMecatalyzed hydration of organonitrile at ambient conditions,Rh(I)OR-catalyzed Aldol-type addition reaction, and Rh(I)OAc-catalyzed rapid hydroboration of vinylarenes are discussed.

机译：1引言布朗斯台德碱和路易斯碱是有机合成中的基准试剂之一，在此我们重点研究基于过渡金属中心和各种类型配体的可微调碱催化剂，该演讲开启了Rh（I）OR的基本性质。讨论了在环境条件下Rh（I）OMe催化有机腈水合，Rh（I）OR催化的Aldol型加成反应和Rh（I）OAc催化的乙烯基芳烃快速硼氢化的代表性结果。

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《18th International Symposium on Fine Chemistry and Functional Polymers,4th IUPAC International Symposium on Novel Materials and Their Synthesis(第18届国际精细化学和功能高分子学术讨论会暨第四届IUPAC 国际新型材料及其制备学术讨论会）》|2008年|33-34|共2页
会议地点 Zhenjiang(CN);Zhenjiang(CN);Zhenjiang(CN);Zhenjiang(CN)
作者
Kohei Endo; Munenao Hirokami; Takanori Shibata;
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作者单位

Department of Chemistry and Biochemistry,School of Advanced Science,Waseda University;

Department of Chemistry and Biochemistry,School of Advanced Science,Waseda University;

Department of Chemistry and Biochemistry,School of Advanced Science,Waseda University;

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正文语种 eng
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关键词
Rhodium; Hydration; Aldol-type addition Reaction; Hydroboration;

机译：铑;水合;羟醛加成反应;硼氢化;

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Rh(I)OR as Finely Tunable Base Catalyst

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