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GaN PHASE FORMATION IN THE HIGH DOSE N-ION IMPLANTED GaP SUBSTRATE

机译:高剂量N离子注入GaP基体中的GaN相形成

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α -GaN phase (wurtzite) was synthesized in GaP (100) by 140 keV N_2~+ ion implantation at 400 ℃ and subsequent furnace annealing (FA) at 950-1000 ℃ for 20 min or rapid thermal annealing (RTA) at 1000 ℃ for 15 sec. N fluence used in the present study was 3.0 X 10~(17) cm~(-2). From X-ray diffraction analysis, the traces of wurtzite-GaN were recognized. Raman spectra were observed at around 525 cm~(-1) together with LO- and TO-phonons from the GaP matrix, indicating the presence of an A_1(TO) mode in GaN. The formation of micro-crystalline GaN of ~1000A in size was confirmed by Auger electron spectroscopy and Transmission electron microscopy analyses. Some diffraction spots from α-GaN were also observed by electron diffraction.
机译:通过在400℃下注入140 keV N_2〜+离子,然后在950-1000℃下进行20分钟的炉内退火(FA)或在1000℃下进行快速热退火(RTA),在GaP(100)中合成α-GaN相(纤锌矿)。持续15秒。本研究中使用的氮通量为3.0 X 10〜(17)cm〜(-2)。通过X射线衍射分析,可以确认纤锌矿型GaN的痕迹。在约525 cm〜(-1)处观察到拉曼光谱,以及来自GaP矩阵的LO-和TO-声子,表明GaN中存在A_1(TO)模式。通过俄歇电子能谱和透射电子显微镜分析证实了〜1000A的微晶GaN的形成。通过电子衍射还观察到一些来自α-GaN的衍射点。

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