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Refinery Off Gas Treatment and Recovery – Challenges of Designing ROG Units

机译:精炼厂废气处理和回收–设计ROG装置的挑战

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Refinery off-gas (ROG) is produced in the refinery units that manufacture conversion productsrnsuch as hydrotreaters, alkylation units, FCC, and Platformers. Valuable products includingrnhydrogen, olefins, natural gas liquids (NGL) and higher Btu fuel gas can be recovered from thernoff-gas if a ROG processing unit is installed. The incremental economics of product recovery asrnopposed to using the entire off-gas for fuel provides the incentives for installation of ROG units.rnThe composition of the refinery off-gas stream will vary appreciably depending on the source.rnThe refinery off-gas may contain a number of trace components such as oxygen, ammonia,rnnitriles, acetylenes, sulfur compounds, butadiene, chlorides, arsenic, mercury, and water inrnaddition to acid gases H2S, CO2, and COS. The specifications of the recovered products andrncatalyst requirements will dictate the allowable limits of these contaminants in the feed streamrnMethods for removal of the individual contaminants in the off-gas are detailed in the paper.rnVarious configurations of the ROG plant and associated units are compared depending on therntype of product and feed stock. Optimization strategies required for the design are alsorndiscussed in the paper.
机译:炼厂废气(ROG)在制造转化产品的炼厂单元中生产,例如加氢处理机,烷基化单元,FCC和Platformer。如果安装了ROG处理单元,则可以从废气中回收包括氢,烯烃,天然气液体(NGL)和更高Btu燃气在内的有价值的产品。由于将全部废气用作燃料,产品回收的增量经济性为安装ROG装置提供了动力。rn精炼厂废气流的组成将根据来源而显着变化。rn精炼厂废气可能包含酸性气体H2S,CO2和COS中添加的微量元素(例如氧气,氨,腈,乙炔,硫化合物,丁二烯,氯化物,砷,汞和水)的回收产品的规格和催化剂的要求将决定允许的含量进料流中这些污染物的限制论文中详细介绍了去除废气中单个污染物的方法。根据产品和原料的类型,对ROG工厂的各种配置和相关单位进行了比较。本文还讨论了设计所需的优化策略。

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