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Electrical properties of polymer coatings modified with nanoadditives

机译:纳米添加剂改性的聚合物涂料的电性能

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Polymer coatings were doped with low quantity, below 1.5% by weight, of metal and non-metal nanoparticles. The electrical properties, i.e. antistatic properties, volume resistance and temperature characteristics of dissipation factor tanδ, were investigated. Antistatic properties were examined by charge decay measurements after corona charging, using JCI 155 apparatus. The results showed that the various additives can increase or decrease the time of charge decay. Incorporation of nanosilica to polymer much deteriorated the antistatic properties, due to barrier properties of nanosilica. On contrary the adding of nanosilver did not elongate the time of charge decay. The volume and surface resistivity at room temperature increases after adding a small amount of the conducting nanoadditives. It was proved that the tantanδ curves of coatings with nanosilica, as opposed to compounds with nanosilver, shift to higher temperatures. Therefore, application of nanosilica into polymer causes that the orientation polarization begin at higher temperature that results in the better thermal stability of modified coating. It was stated that nanosilver can improve antistatic properties without deterioration of dielectric properties of coating. On the other hand nanosilica additive results in the worse antistatic properties.
机译:聚合物涂料中掺有少量金属和非金属纳米粒子,含量低于1.5%(重量)。研究了电性能,即抗静电性能,体积电阻和耗散系数tanδ的温度特性。使用JCI 155仪器在电晕充电后通过电荷衰减测量来检查抗静电性能。结果表明,各种添加剂均可增加或减少电荷衰减时间。由于纳米二氧化硅的阻隔性能,将纳米二氧化硅掺入聚合物中大大降低了抗静电性能。相反,添加纳米银并不能延长电荷衰减的时间。加入少量导电纳米添加剂后,室温下的体积和表面电阻率增加。已经证明,与具有纳米银的化合物相反,具有纳米二氧化硅的涂层的tantanδ曲线向更高的温度移动。因此,将纳米二氧化硅应用到聚合物中导致取向极化在更高的温度下开始,这导致改性涂层的更好的热稳定性。据指出,纳米银可以改善抗静电性能而不会降低涂层的介电性能。另一方面,纳米二氧化硅添加剂导致较差的抗静电性能。

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