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Controlling molecular isomerization and fragmentation with laser-induced electron recollision

机译:用激光诱导的电子碰撞控制分子的异构化和断裂

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Molecular ionization by femtosecond light pulses is fascinating phenomena in terms of both the underlying physics and practical implications to selective control of isomerization and fragmentation pathway(s) through the shape of the optical waveform. Triggered by optical field ionization, the outcome of the complex electronic and subsequent nuclear dynamics leading to fragmentation is to a large extent predetermined on a subcycle time scale because of a sharp temporal localization of electron release to an attosecond interval at the peak of an intense optical half-cycle. Consequently, as has been shown in the case of diatomic molecules[1,2] — dissociative ionization strongly depends on the carrier-envelope phase (CEP) of a few-cycle laser pulse.
机译:飞秒光脉冲引起的分子电离是令人着迷的现象,无论是通过光学波形的形状对异构化和片段化路径的选择性控制的基本物理意义还是实际意义。由光场电离触发,导致碎裂的复杂电子动力学和随后的核动力学结果在很大程度上是在亚周期时间尺度上预先确定的,因为电子释放的剧烈时间局部化在强光的峰值处达到了一个阿秒间隔。半周期。因此,如在双原子分子[1,2]的情况下所示,解离电离强烈取决于几个周期激光脉冲的载流子包络相(CEP)。

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