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Fundamental properties of ferroelectric liquid-crystalline conductive polymers

机译:铁电液晶导电聚合物的基本性能

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Poly(2-methoxy, 5-(4-decyloxy-biphenyl-4′-(1, 10-dioxydecane))-p-phenylenevinylene), MDBD-PPV, wih a long side chain containing alkoxybiphenyl mesogenic unit has been synthesized and its electrical and optical properties have been investigated. This polymer showed a microscopic texture typical to the liquid-crystalline phase and a sharp X-ray diffraction peak due to the smectic layer structure. The band gap of MDBD-PPV in the liquid-crystalline phase has been estimated to be about 2.3 eV. An electroluminescent (EL) device has been fabricated using this liquid-crystalline polymer. MDBD-PPV, as an emissive layer and the polarity effect has been observed in the emission spectra of this EL device.
机译:合成了具有长侧链的含烷氧基联苯介晶单元的聚(2-甲氧基,5-(4-癸氧基联苯-4'-(1,10-二氧癸烷))-对亚苯基亚乙烯基)MDBD-PPV已经研究了电学和光学性质。由于近晶层结构,该聚合物表现出液晶相典型的微观织构和尖锐的X射线衍射峰。估计液晶相中MDBD-PPV的带隙为约2.3eV。使用该液晶聚合物已经制造了电致发光(EL)器件。在该EL器件的发射光谱中已经观察到MDBD-PPV作为发射层,并且极性效应。

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