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A microfluidic device based on plasma nitrided self-organized TiO2 nanotubes for photocatalytic reduction study

机译:基于等离子体氮化的自组织TiO 2 纳米管的微流控装置用于光催化还原研究

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Nitrided TiO2 nanotubes and PDMS microchannel were assembled in a photocatalytic device for organic dyes photo-degradation studies. By integrating a PDMS microchannel with the nitrided TiO2 nanotubes array, a microfluidic photocatalytic device was obtained and characterized by morphological, chemical, and physical points of view. The fabrication process allows an easy integration of the obtained nitrided TiO2 nanotubes with a microchannel into a microfluidic device for pollutant photodegradation. The high surface-to-volume ratio intrinsic in nanotubes structures has functional properties for harvesting light and is responsible for part of the interesting photocatalytic device performance. Another great advantage of nitrided TiO2 nanotubes compared to just TiO2 nanotubes, is the lower gap of 2.80eV achieved by plasma nitriding processes in PECVD reactor, which leads to an increase of 14% in the photocatalytic response to sun light.
机译:在光催化装置中组装了氮化的TiO 2 纳米管和PDMS微通道,用于有机染料的光降解研究。通过将PDMS微通道与氮化的TiO 2 纳米管阵列集成在一起,获得了一种微流体光催化装置,并从形态,化学和物理角度对其进行了表征。制备过程使获得的氮化的TiO 2 纳米管与微通道易于整合到微流控装置中,用于污染物的光降解。纳米管结构中固有的高表面积/体积比具有收集光的功能特性,并且是令人感兴趣的光催化器件性能的一部分。与仅TiO 2 纳米管相比,氮化的TiO 2 纳米管的另一个巨大优势是PECVD反应器中通过等离子体氮化工艺实现的2.80eV的较小间隙,这导致了增加在对太阳光的光催化响应中占14%。

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