Synthesis of acrylic acid via aldol condensation reaction on titanium and mixed vanadium-titanium phosphate catalysts with different porous structure

机译：钛与不同多孔结构的钒钛磷酸盐混合催化剂的羟醛缩合反应合成丙烯酸

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摘要

In this work we present the application of hydrothermal method for synthesis of vanadium, titanium and mixed vanadium-titanium phosphate catalysts and the results of their testing in aldol condensation reaction of acetic acid with formaldehyde to acrylic acid. It was found that porous structure of phosphate catalysts has predominant effect on their catalytic performance in aldol condensation reaction.

机译：在这项工作中，我们介绍了水热法在合成钒，钛和磷酸钒钛混合催化剂中的应用，以及它们在乙酸与甲醛的醛醇缩合反应中合成丙烯酸的测试结果。已经发现，磷酸盐催化剂的多孔结构对其在醛醇缩合反应中的催化性能具有主要影响。

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来源
《2017 IEEE 7th International Conference Nanomaterials: Application amp; Properties》|2017年|1-4|共4页
会议地点 Odessa(UA)
作者
Roman Nebesnyi; Volodymyr Ivasiv; Iryna Shpyrka; Yuliia Nebesna; Volodymyr Sydorchuk; Svitlana Khalameida;
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作者单位

Technology of organic products department Lviv polytechnic National university Lviv, Ukraine;

Technology of organic products department Lviv polytechnic National university Lviv, Ukraine;

Technology of organic products department Lviv polytechnic National university Lviv, Ukraine;

Technology of organic products department Lviv polytechnic National university Lviv, Ukraine;

Institute of Sorption and Problems of Endoecology National Academy of Science of Ukraine Kyiv, Ukraine;

Institute of Sorption and Problems of Endoecology National Academy of Science of Ukraine Kyiv, Ukraine;

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原文格式 PDF
正文语种 eng
中图分类
关键词
Titanium; Surface treatment; Conferences; Nanomaterials; Vanadium; Production; Compounds;

机译：钛;表面处理;会议;纳米材料;钒;生产;化合物;;

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专利

1. Preparation of two different crystal structures of cerous phosphate as solid acid catalysts: their different catalytic performance in the aldol condensation reaction between furfural and acetone [J] . Li Wenzhi, Su Mingxue, Yang Tao, RSC Advances . 2019,第30期

机译：用磷酸盐磷酸盐两种不同晶体结构的制备：糠醛和丙酮之间的醛醇缩合反应中的不同催化性能
2. Preparation of two different crystal structures of cerous phosphate as solid acid catalysts: their different catalytic performance in the aldol condensation reaction between furfural and acetone [J] . Wenzhi Li, Mingxue Su, Tao Yang, RSC Advances . 2019,第30期

机译：固体酸催化剂磷酸铈的两种不同晶体结构的制备：它们在糠醛与丙酮的醛醇缩合反应中的不同催化性能
3. Aldol condensation reactions of acetone and formaldehyde over vanadium phosphate catalysts: Comments on the acid-base properties [J] . Richard Tanner, Philip Gill, Richard Wells, Physical chemistry chemical physics: PCCP . 2002,第4期

机译：丙酮和甲醛在磷酸钒催化剂上的醛醇缩合反应：关于酸碱性质的评论
4. Synthesis of acrylic acid via aldol condensation reaction on titanium and mixed vanadium-titanium phosphate catalysts with different porous structure [C] . Roman Nebesnyi, Volodymyr Ivasiv, Iryna Shpyrka, International Conference on Nanomaterials: Application Properties . 2017

机译：用不同多孔结构对钛和混合钒 - 磷酸钛磷酸钛催化剂的丙烯酸合成丙烯酸
5. Novel cinchona alkaloid derived ammonium salts as phase-transfer catalysts for the asymmetric synthesis of beta-hydroxy alpha-amino acids via aldol reactions and total synthesis of celogentin C. [D] . Ma, Bing. 2009

机译：新型金鸡纳生物碱衍生的铵盐作为相转移催化剂，用于通过醛醇缩合反应不对称合成β-羟基α-氨基酸和全合成celogentinC。
6. Novel Cinchona alkaloid derived ammonium salts as catalysts for the asymmetric synthesis of β-hydroxy α-amino acids via aldol reactions [O] . Bing Ma, Jared L. Parkinson, Steven L. Castle -1

机译：新型金鸡纳生物碱衍生的铵盐作为通过醛醇缩合反应不对称合成β-羟基α-氨基酸的催化剂
7. Preparation of two different crystal structures of cerous phosphate as solid acid catalysts: their different catalytic performance in the aldol condensation reaction between furfural and acetone [O] . Wenzhi Li, Mingxue Su, Tao Yang, 2019

机译：用磷酸盐磷酸盐两种不同晶体结构的制备：糠醛和丙酮之间的醛醇缩合反应中的不同催化性能

Synthesis of acrylic acid via aldol condensation reaction on titanium and mixed vanadium-titanium phosphate catalysts with different porous structure

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