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GASIFICATION OF SOLID RECOVERED FUELS IN A LAB-SCALE FLUIDIZED BED REACTOR. EFFECT OF EXPERIMENTAL CONDITIONS ON PROCESS PERFORMANCE AND SYNGAS QUALITY

机译:实验室规模的流化床反应器中固体回收燃料的气化。实验条件对过程性能和语法质量的影响

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摘要

This paper studied the gasification of two solid recovered fuels (SRF) in a laboratory scale fluidizedrnbed reactor. The gasification performance and syngas quality were assessed under the influence of severalrnparameters: gasification temperature (from 700 to 850 ℃), equivalence ratio (ER, 0.22-0.35), SRF feedstock (RT orrnFL), bed material (sand or dolomite) and gasification agent (air or oxygen/steam). Special attention was devoted tornthe evolution of tar and microcontaminants concentration (H_2S, HCN, HCl and NH_3) in the syngas. The resultsrnindicated that increasing gasification temperature and ER led to higher gas yields and H_2/CO ratios whereas tarrncontent decreased. In general, the predominant levels of HCl and HCN in the producer gas tended to diminish at thesernconditions meanwhile H_2S slightly increased and NH_3 was scarcely detected. Other parameters affecting positivelyrnthe gasification performance were the use of dolomite as bed material and the use of oxygen/steam as gasificationrnagent, enhancing tar cracking and reforming reactions. This study provides insight into the evolution of the studiedrnmicrocontaminants under different experimental conditions and reports recommendations about the gasificationrnconditions in order to improve gasification performance and gas quality for two different SRF.
机译:本文研究了在实验室规模的流化床反应器中两种固体回收燃料的气化。在以下几个参数的影响下评估了气化性能和合成气质量:气化温度(700至850℃),当量比(ER,0.22-0.35),SRF原料(RT orrnFL),床料(砂或白云石)和气化剂(空气或氧气/蒸汽)。特别关注了合成气中焦油和微污染物浓度(H_2S,HCN,HCl和NH_3)的释放。结果表明,气化温度和ER的升高导致更高的气体产率和H_2 / CO比,而焦油含量降低。通常,在某些条件下,生产气中的主要HCl和HCN含量趋于减少,而H_2S略有增加,而几乎未检测到NH_3。影响气化性能的其他参数还包括使用白云石作为床层材料以及使用氧气/蒸汽作为气化剂,从而提高了焦油裂解和重整反应的效率。这项研究提供了对不同实验条件下所研究微污染物演变的见解,并报告了有关气化条件的建议,以改善两种不同SRF的气化性能和气体质量。

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  • 来源
  • 会议地点 Vienna(AT)
  • 作者单位

    Departament d’Enginyeria Química. Universitat Rovira i Virgili. Av. Països Catalans, 26. Tarragona, 43007 Spain;

    Thermochemical Conversion Group. Catalonia Institute for Energy Research, IREC.C/ Marcel·lí Domingo, 2. Tarragona, 43007 Spain Phone: +34 977297921 Fax: +34 977202444 E-mail: cberrueco@irec.cat;

    Departament d’Enginyeria Química. Universitat Rovira I Virgili. Av. Països Catalans, 26. Tarragona, 43007 Spain Thermochemical Conversion Group. Catalonia Institute for Energy Research, IREC.C/ Marcel·lí Domingo, 2. Tarragona, 43007 Spain;

    Departament d’Enginyeria Química. Universitat Rovira I Virgili. Av. Països Catalans, 26. Tarragona, 43007 Spain;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    gasification; municipal solid waste (MSW); performance; syngas; quality;

    机译:气化;市政固体废物(MSW);性能;合成气;质量;

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