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CORROSION OF TYPE 304L STAINLESS STEEL IN BOILING DILUTE NEPTUNIUM NITRATE SOLUTION

机译:304L型不锈钢在沸腾稀硝酸钕溶液中的腐蚀

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摘要

Corrosion of type 304L stainless steel in nitric acid solution containing neptunium was studied under immersion and heat-transfer condition. Corrosion rates of stainless steel were obtained by the weight loss measurement and the quantitative analysis of metallic ions dissolved in solution. The surface morphology was observed by scanning electron microscopy. The corrosion acceleration mechanism was investigated by polarization measurement and spectrophotometry. The corrosion rate in boiling 9M nitric acid was accelerated by addition of neptunium. The corrosion of stainless steel was promoted under heat-transfer condition compared to immersion condition. In polarization measurements, the cathodic current was increased by addition of neptunium. Spectrophotometric measurements showed the oxidization of neptunium in boiling nitric acid. It was suggested that the accelerated corrosion in nitric acid solution containing neptunium was caused by re-oxidation of neptunium.
机译:研究了浸入和传热条件下304L不锈钢在含n的硝酸溶液中的腐蚀情况。通过重量损失测量和对溶解在溶液中的金属离子的定量分析,可以获得不锈钢的腐蚀速率。通过扫描电子显微镜观察表面形态。通过极化测量和分光光度法研究了腐蚀促进机理。通过添加n加快了沸腾的9M硝酸中的腐蚀速率。与浸入条件相比,在传热条件下促进了不锈钢的腐蚀。在极化测量中,阴极电流通过添加n而增加。分光光度法测量表明boiling在沸腾的硝酸中被氧化。有人认为,在含有containing的硝酸溶液中加速腐蚀是由于re的再氧化引起的。

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