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An Adsorptive Reactor for Operation of Exothermic Series Reactions

机译:用于放热系列反应的吸附反应器

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In the case investigated a feed mixture is utilized consisting of species A and B, whereby the objective is to maximize the conversion of A with a reactant D and to minimize the conversion of species B with the same reactant D. This is accomplished by in-situ pre-separation of species A by adsorption at high pressure and subsequent desorption and simultaneous reaction of A and D. In this way the conversion of B is effectively counteracted. We have explicitly considered the impact of temperature gradients arising from the heat of reaction and adsorption. The above mentioned configuration is bench marked against a system with ex-situ pre-separation, using a PSA unit, and a plug flow reactor in series. We show that the adsorptive reactor system can be a viable reactor configuration in case of exothermic series reaction as it may allow increased intermediate product selectivity.
机译:在所研究的情况下,使用了由物质A和B组成的进料混合物,目的是使A与反应物D的转化最大化,并使B与相同反应物D的转化最小。通过高压吸附原位预分离物种A,随后解吸以及A和D同时反应。这样可以有效地抵消B的转化。我们已经明确考虑了反应和吸附热引起的温度梯度的影响。使用PSA单元和串联的活塞流反应器,将上述配置标记为带有异位预分离系统的工作台。我们表明,在放热串联反应的情况下,吸附反应器系统可以是可行的反应器配置,因为它可以增加中间产物的选择性。

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