PLASTICIZED PROTON CONDUCTING POLYMER ELECTROLYTES BASED ON POLYETHYLENE OXIDE AND AMMONIUM SALTS NH_4X: X=F~-, BF_4~-

机译：基于聚环氧乙烷和铵盐NH_4X的质子化质子传导聚合物电解质：X = F〜-，BF_4〜-

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Polymer electrolytes containing polyethylene oxide (PEO) and ammonium salts (NH_4F and NH_4BF_4) have been studied and found to have room temperature conductivity of the order of 10~(-6) - 10~(-5) S/cm. The addition of plasticizers having different dielectric constant and viscosity values has been found to modify the conductivity of polymer electrolytes. The increase in conductivity with plasticizer addition has been found to depend upon (ⅰ) the amount of salt present, (ⅱ) amount of plasticizer added and (ⅲ) the nature of plasticizer used. Preliminary NMR studies show that these polymer electrolytes are proton conductors.

机译：研究了包含聚环氧乙烷（PEO）和铵盐（NH_4F和NH_4BF_4）的聚合物电解质，其室温电导率约为10〜（-6）-10〜（-5）S / cm。已经发现添加具有不同介电常数和粘度值的增塑剂可以改变聚合物电解质的电导率。已经发现，随着增塑剂的添加，电导率的增加取决于（ⅰ）存在的盐的量，（ⅱ）所添加的增塑剂的量和（ⅲ）所使用的增塑剂的性质。 NMR的初步研究表明，这些聚合物电解质是质子导体。

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来源
《8th Asian Conference on Solid State Ionics: Trends in the New Millennium; Dec 15-19, 2002; Langkawi, Malaysia》|2002年|p.377-384|共8页
会议地点 Langkaw(MY)
作者
S. S. SEKHON; MANOJ KUMAR;
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Department of Applied Physics, G. N. D. University, Amritsar- 143005, INDIA;

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原文格式 PDF
正文语种 eng
中图分类物理学;
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7. Drawbacks of Low Lattice Energy Ammonium Salts for Ion-Conducting Polymer Electrolyte Preparation: Structural, Morphological and Electrical Characteristics of CS:PEO:NH4BF4-Based Polymer Blend Electrolytes [O] . Mohamad A. Brza, Shujahadeen B. Aziz, Muaffaq M. Nofal, 2020

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PLASTICIZED PROTON CONDUCTING POLYMER ELECTROLYTES BASED ON POLYETHYLENE OXIDE AND AMMONIUM SALTS NH_4X: X=F~-, BF_4~-

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