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首页> 外文会议>8th Asian Conference on Solid State Ionics: Trends in the New Millennium; Dec 15-19, 2002; Langkawi, Malaysia >SOLED STATE BATTERY DISCHARGE CHARACTERISTIC STUDIES ON SOME NEW Ag~+ ION CONDUCTING GLASSES
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SOLED STATE BATTERY DISCHARGE CHARACTERISTIC STUDIES ON SOME NEW Ag~+ ION CONDUCTING GLASSES

机译：新型新型Ag〜+离子导电玻璃的固态电池放电特性研究

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摘要

Investigations on discharge behavior and cell performance for following two solid state batteries, in the cell configuration: Cell Ⅰ: Ag (Anode)/ 0.7[0.75AgI: 0.25AgCl]: 0.3[Ag_2O: WO_3]/ (C + I_2) (Cathode) Cell Ⅱ: Ag (Anode)/ 0.8[0.75AgI: 0.25AgCl]: 0.2[Ag_2O: MoO_3]/ (C + I_2) (Cathode) are reported. The two new fast Ag~+ ion conducting glass systems, prepared using an alternate host: " a quenched [0.75AgI: 0.25AgCl] mixed system/ solid solution" in place of the traditional host AgI, were used as a solid electrolytes. Extensive studies on the ion transport behavior of these systems have been done and reported elsewhere in the literature. The study of the potential discharge profiles of the above batteries under varying load conditions revealed the fact that these batteries can be used purposefully under low current drain conditions. Ionic transference number (t_(ion)) measurements was also done with the help of theoretical and observed values of open circuit voltages (OCVs). It was observed that t_(ion) ～ 1, for both the systems. This is in agreement with the value obtained earlier by Wagner's method and indicative of the fact that Ag~+ ions are the sole charge carriers in the systems with negligible electronic contribution.
机译：以下两个固态电池在电池配置中的放电行为和电池性能的研究：电池Ⅰ：Ag（阳极）/ 0.7 [0.75AgI：0.25AgCl]：0.3 [Ag_2O：WO_3] /（C + I_2）（阴极）报告了单元Ⅱ：Ag（阳极）/0.8 [0.75AgI：0.25AgCl]：0.2 [Ag_2O：MoO_3] /（C + I_2）（阴极）。使用替代的主体：“淬灭的[0.75AgI：0.25AgCl]混合系统/固溶体”代替传统的主体AgI制备的两种新型的快速Ag〜+离子导电玻璃系统被用作固体电解质。已经对这些系统的离子传输行为进行了广泛的研究，并在其他文献中进行了报道。对上述电池在变化的负载条件下的潜在放电曲线的研究表明，可以在低电流消耗条件下有目的地使用这些电池。离子转移数（t_（ion））的测量也借助于开路电压（OCV）的理论值和观察值进行。观察到两个系统的t_（ion）〜1。这与早先通过Wagner方法获得的值是一致的，并且表明以下事实，即Ag〜+离子是系统中电子贡献微不足道的唯一电荷载体。

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