IMPEDANCE SPECTROSCOPY AND STRUCTURAL INVESTIGATION OF Li~+ CONDUCTOR Li_3InBr_6

机译：Li〜+导体Li_3InBr_6的阻抗谱和结构研究

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Li_3InBr_6 undergoes phase transition to a superionic conductor at 314 K. This high-temperature phase cooled down to room temperature shows an extremely high conductivity 5.0x10~(-4) Scm~(-1) at 300 K. The temperature dependence of the X-ray powder diffraction suggested that the HT phase changes its structure gradually with temperature and finally showed simple powder pattern of the NaCl structure at 420 K. This structure contains intrinsic vacancies because of the substitution, 3Li~+ = In~(3+). A sharp ~(115)In NMR also supported this average structure for the HT phase.

机译：Li_3InBr_6在314 K处发生相转变为超离子导体。冷却至室温的高温相在300 K处显示出极高的电导率5.0x10〜（-4）Scm〜（-1）。X的温度依赖性射线粉末衍射表明，HT相随温度逐渐改变其结构，并最终在420 K处显示出简单的NaCl结构粉末图。该结构由于取代3Li〜+ = In〜（3+）而具有固有的空位。尖锐的〜（115）In NMR也支持HT相的这种平均结构。

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来源
《8th Asian Conference on Solid State Ionics: Trends in the New Millennium; Dec 15-19, 2002; Langkawi, Malaysia》|2002年|p.621-628|共8页
会议地点 Langkaw(MY)
作者
K. YAMADA; K. IWAKI; T. OKUDA; Y. TOMITA;
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作者单位

Graduate School of Science, Hiroshima University, Kagamiyama 1-3, 739-8526 Higashi-Hiroshima, Japan;

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原文格式 PDF
正文语种 eng
中图分类物理学;
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IMPEDANCE SPECTROSCOPY AND STRUCTURAL INVESTIGATION OF Li~+ CONDUCTOR Li_3InBr_6

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