Solubility of Gases and Vapors in Glassy Polymer Blends

机译：气体和蒸气在玻璃状聚合物共混物中的溶解度

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The solubility of gases and vapors in miscible polymer blends in the glassy state has been considered. The sorption isotherms are calculated using an extension of the NELF model to polymer blends for both nonswelling and swelling penetrants. The swelling coefficient for the blend is given in terms of the swelling coefficients for the pure polymers. In all cases, the isotherms for the polymer blends can be completely predicted based on the parameters needed for the solubility in the pure polymer. The comparison between the model predictions and experimental data for PS-TMPC blends are shown in detail and indicate the reliability of the model.

机译：已经考虑了气体和蒸气在玻璃态下在可混溶的聚合物共混物中的溶解性。吸附等温线是使用NELF模型扩展到非溶胀和溶胀渗透剂的聚合物共混物来计算的。共混物的溶胀系数根据纯聚合物的溶胀系数给出。在所有情况下，都可以根据纯聚合物中溶解度所需的参数完全预测聚合物共混物的等温线。详细显示了PS-TMPC共混物的模型预测与实验数据之间的比较，并表明了模型的可靠性。

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来源
《American Chemical Society Meeting on Advanced Materials for Membrane Separations; 2001; Chicago,IL; US》|2001年|P.55-73|共19页
会议地点 Chicago IL(US);Chicago IL(US)
作者
F. Grassia; M. Giacinti Baschetti; F. Doghieri; G. C. Sarti;
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Dipartimento di Ingegneria Chimica, Mineraria e delle Tecnologie Ambientali, Alma Mater Studiorum, Universita di Bologna, Viale Risorgimento 2, 40136 Bologna, Italy;

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正文语种 eng
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1. Solubility of gases and vapors in glassy polymers modelled through non-equilibrium PHSC theory [J] . Doghieri F, De Angelis MG, Baschetti MG, Fluid Phase Equilibria . 2006,第1a2期

机译：通过非平衡PHSC理论模拟的玻璃态聚合物中气体和蒸汽的溶解度
2. IUPAC-NIST Solubility Data Series 70. Solubility of Gases in Glassy Polymers [J] . Russell Paterson, Yuri Yampolskii, Peter G.T.Fogg, Journal of Physical and Chemical Reference Data . 1999,第5期

机译：IUPAC-NIST溶解度数据系列70.气体在玻璃状聚合物中的溶解度
3. Predictive model for gas and vapor solubility and swelling in glassy polymers I: Application to different polymer/penetrant systems [J] . Minelli Matteo, Doghieri Ferruccio Fluid Phase Equilibria . 2014,第Null期

机译：玻璃态聚合物中气体和蒸气溶解度和溶胀的预测模型I：在不同聚合物/渗透剂体系中的应用
4. Solubility of Gases and Vapors in Glassy Polymer Blends [C] . F. Grassia, M. Giacinti Baschetti, F. Doghieri, American Chemical Society . 2004

机译：气体和蒸汽在玻璃聚合物共混物中的溶解度
5. SOLUBILITY CALCULATIONS FOR ACID GASES IN AMINE BLENDS (PHASE EQUILIBRIA, TREATING). [D] . CHAKRAVARTY, TANMOY. 1985

机译：胺混合物中酸气的溶解度计算（相平衡，处理）。
6. Development of a Chemiresistor Sensor Based on Polymers-Dye Blend for Detection of Ethanol Vapor [O] . Marcos A. L. dos Reis, Fabiano Thomazi, Jordan Del Nero, 2010

机译：基于聚合物-染料共混物的化学传感器检测乙醇蒸气的开发
7. Predictive Calculations of the Solubility of Gases and Vapours in Glassy Polymers: An Overview [O] . Sarti G.C. 2012

机译：玻璃态聚合物中气体和蒸气的溶解度的预测计算：概述
8. Gas Solubility in Glassy Polymers - A Correlation with Excess Enthalpy. [R] . Rein, D. H., Baddour, R. F., Cohen, R. E. 1990

机译：玻璃态聚合物中的气体溶解度 - 与过量焓的相关性。

Solubility of Gases and Vapors in Glassy Polymer Blends

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