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Recycle of Uranium in Fission Products

机译:裂变产品中的铀回收

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摘要

A method for decontaminating uranium product from the Purex process comprises addition of hydrazine to the product uranyl nitrate stream from the Purex process, which contains hexavalent (UO.sub.2.sup.2+) uranium and heptavalent technetium (TcO.sub.4 -). Technetium in the product stream is reduced and then complexed by the addition of oxalic acid (H.sub.2 C.sub.2 O.sub.4), and the Tc-oxalate complex is readily separated from the uranium by solvent extraction with 30 vol. % tributyl phosphate in n-dodecane. Process design analyses are presented to optimize the reclamation. Another case study of decontaminating the soil of nuclear wastes is discussed.
机译:一种对Purex工艺中的铀产品进行净化的方法,包括将肼添加到Purex工艺中的产品硝酸铀酰流中,该物流中含有六价(UO.sub.2.sup.2 +)铀和七价tech(TcO.sub.4) -)。还原产物流中的reduced,然后通过添加草酸(H.2 C.sub.2 O.sub.4)使其络合,并通过用溶剂萃取法从铀中轻松分离出Tc-草酸盐络合物30卷在正十二烷中的%磷酸三丁酯。提出了工艺设计分析以优化回收。讨论了净化核废料土壤的另一个案例研究。

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