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Parametric studies of the Direct Alcohol Phosphoric Acid Fuel Cell

机译:直接酒精磷酸燃料电池的参数研究

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摘要

Higher temperature alcohol fuel cells have been shown to have higher activity and increased performance output when compared to lower temperature alcohol fuel cells. In this work, the Direct Alcohol Phosphoric Acid Fuel Cell (DAPAFC) with Pt Black as catalyst and Phosphoric Acid/Silicon Cabride (SiC) as an electrolyte/separator is investigated. Parametric studies are conducted to demonstrate the effects of such parameters as the stream pressures, higher temperature operation (120-180℃), and the thickness of the SiC separator, etc. Results show that the cell performance is comparable to that of a vapour fed fuel cell with Nafion~® membrane at the same operating conditions. However the DAP AFC has the ability to go to a higher temperature range because its conductivity is independent of water content. This type of fuel cell demonstrates stability with performance degradation less than 7 mV/hr and performance improvement in a higher temperature range when compared to the conventional PEMFC.
机译:与低温酒精燃料电池相比,高温酒精燃料电池已显示具有更高的活性和更高的性能输出。在这项工作中,研究了以Pt Black为催化剂并以磷酸/硅碳氢化物(SiC)作为电解质/隔板的直接酒精磷酸燃料电池(DAPAFC)。进行了参数研究,证明了诸如流压,更高的工作温度(120-180℃)以及SiC隔板的厚度等参数的影响。结果表明,电池性能可与蒸汽进料的性能相媲美。带有Nafion〜®膜的燃料电池在相同的运行条件下。但是,DAP AFC具有更高的温度范围,因为其电导率与水含量无关。与传统的PEMFC相比,这种类型的燃料电池表现出稳定性,性能下降小于7 mV / hr,并且在更高的温度范围内性能得到改善。

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  • 来源
  • 会议地点 Vancouver(CA);Vancouver(CA)
  • 作者单位

    Department of Chemical and Biological Engineering, University of British Columbia,Vancouver, British Columbia, V6T 1Z3, Canada,Clean Energy Research Centre, University of British Columbia, Vancouver, British Columbia, V6T 1Z3, Canada,National Research Council - Institute for Fuel Cell Innovation, Vancouver, British Columbia, V6T R15, Canada;

    Department of Chemical and Biological Engineering, University of British Columbia,Vancouver, British Columbia, V6T 1Z3, Canada,Clean Energy Research Centre, University of British Columbia, Vancouver, British Columbia, V6T 1Z3, Canada,National Research Council - Institute for Fuel Cell Innovation, Vancouver, British Columbia, V6T R15, Canada;

    Clean Energy Research Centre, University of British Columbia, Vancouver, British Columbia, V6T 1Z3, Canada;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 独立电源技术(直接发电);
  • 关键词

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