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Long-Term Stability of Nafion Hybrid Membranes for Use in Vanadium Redox-Flow Batteries

机译:用于钒氧化还原流电池的Nafion混合膜的长期稳定性

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摘要

The membrane is the key component of a redox-flow system. It should possess high proton conductivity and should avoid cross contamination due to the diffusion of ions of the active material through membrane pores. A membrane with drastically reduced cross contamination ability would overcome the main problem of several redox couples and in consequence it would allow redox-flow systems with higher energy density and lower material costs. In previous works cross contamination of Nafion membranes could have been reduces significantly by several modification methods with SiO2 nano particles. This work deals with the long-term stability of this improvement that was investigated by cycling modified membranes for several weeks and analyzing the electrical performance in dependency of time. Nafion membrane modified with TEOS/DEDMS/NH3 showed a very good long-term stability.
机译:膜是氧化还原流系统的关键组成部分。它应具有高质子传导性,并应避免由于活性物质离子通过膜孔的扩散而引起的交叉污染。具有大大降低的交叉污染能力的膜将克服几个氧化还原对的主要问题,因此,它将使氧化还原流系统具有更高的能量密度和更低的材料成本。在以前的工作中,Nafion膜的交叉污染可以通过使用SiO2纳米颗粒的几种改性方法大大降低。这项工作涉及这种改进的长期稳定性,该改进是通过将改性膜循环数周并分析随时间变化的电性能来进行研究的。用TEOS / DEDMS / NH3改性的Nafion膜显示出非常好的长期稳定性。

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  • 来源
  • 会议地点 Vancouver(CA);Vancouver(CA)
  • 作者单位

    Electrochemical Energy Conversion and Storage Systems group,Institute for Power Electronics and Electrical Drives (ISEA),RWTH Aachen University, GERMANY;

    Institute for Power Generation and Storage Systems (PGS),E.ON Energy Research Center,RWTH Aachen University, GERMANY;

    Electrochemical Energy Conversion and Storage Systems group,Institute for Power Electronics and Electrical Drives (ISEA),RWTH Aachen University, GERMANY,Institute for Power Generation and Storage Systems (PGS),E.ON Energy Research Center,RWTH Aachen University, GERMANY;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 独立电源技术(直接发电);
  • 关键词

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