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CONTROL OF INTERFACE FRACTURE IN SILICON NITRIDE CERAMICS: INFLUENCE OF DIFFERENT RARE EARTH ELEMENTS

机译:氮化硅陶瓷界面断裂的控制:不同稀土元素的影响

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摘要

In Si_3N_(4(whisker))/oxynitride-glass model systems, interfacial debonding behavior is determined by the interfacial microstructure and chemistry. In Si-Al-RE(Y)-O-N glasses, the interfacial debonding energy increases significantly with SiAlON formation. Al-free glasses enhances interfacial debonding by inhibiting SiAlON formation. Compared to the interfacial microstructure/chemistry, the residual thermal mismatch stresses is a secondary influence on the debonding behavior. In systems without SiAlON formation, the residual stresses modify the debonding length. In self-reinforced silicon nitride ceramics, a higher yttria to alumina additive ratios resulted in a higher steady state toughness. Sophisticated experimental and analytical-modeling work are required to understand the influence of the residual stresses on the interfacial fracture behavior in self-reinforced silicon nitride ceramics.
机译:在Si_3N_(4(晶须))/氮氧化物-玻璃模型系统中,界面剥离行为由界面微观结构和化学性质决定。在Si-Al-RE(Y)-O-N玻璃中,随着SiAlON的形成,界面剥离能显着增加。无铝玻璃通过抑制SiAlON的形成来增强界面剥离力。与界面微观结构/化学性质相比,残余的热失配应力是对剥离性能的次要影响。在没有形成SiAlON的系统中,残余应力会改变剥离长度。在自增强氮化硅陶瓷中,较高的氧化钇与氧化铝的添加比例导致较高的稳态韧性。需要进行复杂的实验和分析建模工作,以了解残余应力对自增强氮化硅陶瓷界面断裂行为的影响。

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  • 来源
  • 会议地点 Berkeley CA(US)
  • 作者单位

    Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge,Tennessee 37831-6068;

    Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge,Tennessee 37831-6068;

    Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge,Tennessee 37831-6068;

    Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge,Tennessee 37831-6068;

    Metals and Ceramics Division, Oak Ridge National Laboratory, Oak Ridge,Tennessee 37831-6068;

    University of Karlsruhe, Institute for Ceramics in Mechanical Engineering,Karlsruhe, Germany;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 TQ174.01;
  • 关键词

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