Silver(I)-selective PVC membrane electrodes based on macrocyclic schiff bases

机译：基于大环席夫碱的银（I）选择性PVC膜电极

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The potentionetric characteristics of poly (vinyl chloride)(PVC) membreane electrodes based on three different sizes of macrocyclic Schiff bases are described.The electrode incorporating a 12-membered macrocyclic Schiff base shows a near Nernstianresponse towards silver (I) ranging from 1x10~-6 to 1x10~-1 mol L~-1 with a slope of 54.5 mB decade~-1 and high selectivity over various ions including Hg~2+,Pb~2+,and Cd~2+.The electrode based on a 14 or 18-membered macrocyclic Schiff base displays ratehr poor response towards silver (I).

机译：描述了基于三种不同大小的大环席夫碱的聚氯乙烯（PVC）膜电极的电位特性。包含12元大环席夫碱的电极显示出对银（I）的近似Nernstian响应，范围为1x10〜- 6至1x10〜-1 mol L〜-1，具有54.5 mB十进制〜-1的斜率，并且对包括Hg〜2 +，Pb〜2 +和Cd〜2 +在内的各种离子具有高选择性。基于14或18元大环席夫碱显示对银（I）的反应速率较差。

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来源
《International meeting on chemical sensors》|1998年|p.503-505|共3页
会议地点 Beijing(CN)
作者
M.Ying; Z.Q.Fan; C.Tang; G.L.Shen; R.Q.Yu;
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原文格式 PDF
正文语种 eng
中图分类自动化技术、计算机技术;
关键词
Macrocyclic Schiff bases; PVC membrane electrode; Silver(I);

机译：大环席夫碱； PVC膜电极；银（I）;

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机译：基于席夫碱（N〜2E，N〜2'E）-N〜2，N〜2-双（噻吩-2-基亚甲基）-1,1'-联萘基的新型银（I）离子选择性PVC膜电极-2,2'-二胺
2. A New PVC-Membrane Electrode Based on a Thia-Substituted Macrocyclic Diamide for Selective Potentiometric Determination of Silver Ion [J] . Hashem Sharghi, Khodabaksh Niknam, Mojtaba Shamsipur, Bulletin of the Korean Chemical Society . 2002,第1期

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3. Comparative evaluation of Dy(III) selective poly(vinyl) chloride based membrane electrodes of macrocyclic tetraimine Schiff's bases [J] . V.K. Gupta, Manoj K. Pal, Ashok K. Singh Talanta: The International Journal of Pure and Applied Analytical Chemistry . 2009,第2期

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4. Silver(I)-selective PVC membrane electrodes based on macrocyclic schiff bases [C] . M.Ying, Z.Q.Fan, C.Tang, International meeting on chemical sensors . 1998

机译：基于大环席夫底座的银（I）光学膜电极
5. Acyclic and macrocyclic tetradentate Schiff base complexes of copper, nickel, and iron: Their synthesis and characterization. [D] . Prytkov, Sergey Yevgenyevich. 1998

机译：铜，镍和铁的无环和大环四齿席夫碱配合物：它们的合成和表征。
6. Preparation of PbS Nanoparticles by Phase-Transfer Method and Application to Pb2+-Selective Electrode Based on PVC Membrane [O] . Weihong Song, Chunhui Wu, Hongzong Yin, -1

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7. Comparative evaluation of Dy(III) selective poly(vinyl) chloride based membrane electrodes of macrocyclic tetraimine Schiff’s bases [O] . K. Gupta Vinod, K. Pal Manoj, K. Singh Ashok 2009

机译：基于Dy（III）选择性聚（乙烯基）氯化物的大环四亚胺schiff碱膜电极的比较评价

Silver(I)-selective PVC membrane electrodes based on macrocyclic schiff bases

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