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Poly(4-vinylpyridine) as a platform for robust CO_2 electroreduction

机译:聚(4-乙烯基吡啶)作为强大的CO_2电还原的平台

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摘要

The development of efficient and robust catalysts is critical for the viability of the electrocatalytic conversion of CO_2 into useful chemicals. Herein, we discover a new class of metal-polymer electrocatalysts with incorporated mechanisms of their stabilization which is based on a poly(4-vinyl pyridine). We attribute the outstanding catalytic properties of the new hybrid material to new intrinsic mechanisms of the metal stabilization offered by the N-heteroaromatic polymer. More generally, our study offers a new simple strategy to design and prepare robust CO_2 reduction electrocatalysts.
机译:有效和耐用的催化剂的开发对于将CO_2电催化转化为有用化学品的可行性至关重要。在这里,我们发现了一类新型的金属聚合物电催化剂,其具有基于聚(4-乙烯基吡啶)的稳定化作用。我们将新型杂化材料的出色催化性能归因于N-杂芳族聚合物提供的金属稳定化的新内在机理。更一般而言,我们的研究提供了一种设计和制备坚固的CO_2还原电催化剂的新的简单策略。

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  • 来源
  • 会议地点 Santa Ana Pueblo NM(US)
  • 作者单位

    Department of Earth and Environmental Engineering, Columbia University, New York, New York, 10027, United States of America;

    Department of Chemical and Petroleum Engineering, University of Calgary, Calgary T2N 1N4 Canada;

    Department of Earth and Environmental Engineering, Columbia University, New York, New York, 10027, United States of America;

    Department of Earth and Environmental Engineering, Columbia University, New York, New York, 10027, United States of America;

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  • 正文语种 eng
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