• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文会议>Compound semiconductors: thin-film photovoltaics, LEDs, and smart energy controls >Fabrication and Characterization of Low-Cost, Large-Area Spray Deposited Cu_2ZnSnS_4 Thin Films for Heterojunction Solar Cells
【24h】

Fabrication and Characterization of Low-Cost, Large-Area Spray Deposited Cu_2ZnSnS_4 Thin Films for Heterojunction Solar Cells

机译：用于异质结太阳能电池的低成本，大面积喷射沉积Cu_2ZnSnS_4薄膜的制备与表征

获取原文
获取原文并翻译 | 示例
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Large-area Cu_2ZnSnS_4 (CZTS) thin films were deposited by low-cost spray pyrolysis technique on Mo-coated soda-lime glass (SLG) substrates at varied substrate temperatures of 563-703°K. Deposition conditions were optimized to obtain best quality films and effect of post deposition thermal processing of the as-deposited films under H_2S ambient were investigated. Structural, morphological, and compositional characterization of as-deposited and H_2S treated CZTS absorber layers were carried out by x-ray diffraction (XRD), Raman spectroscopy, scanning electron microscopy (SEM) and energy dispersive x-ray analysis (EDX). Optical and electrical properties were measured by UV-Vis spectroscopy, van der Pauw, and Hall-effect measurements. Films grown at ～360℃ substrate temperature showed superior optoelectronic properties, improved stoichiometry and smoother morphology compared to films grown at much higher or lower temperatures. Film properties were significantly improved after the H_2S processing. Our results show that large area high quality CZTS films can be fabricated by low-cost spray pyrolysis technique for high throughput commercial production of CZTS based heterojunction solar cells.
机译：通过低成本的喷雾热解技术，在563-703°K的不同衬底温度下，将Mo_2涂覆的钠钙玻璃（SLG）衬底上沉积大面积Cu_2ZnSnS_4（CZTS）薄膜。优化沉积条件以获得最佳质量的薄膜，并研究了在H_2S环境下沉积后薄膜的沉积后热处理的效果。通过X射线衍射（XRD），拉曼光谱，扫描电子显微镜（SEM）和能量色散X射线分析（EDX）对沉积和经H_2S处理的CZTS吸收层进行结构，形态和成分表征。光学和电学性质通过UV-Vis光谱，van der Pauw和霍尔效应测量进行测量。与在更高或更低的温度下生长的薄膜相比，在〜360℃的衬底温度下生长的薄膜显示出优异的光电性能，改进的化学计量比和更平滑的形态。 H_2S处理后，薄膜的性能得到明显改善。我们的结果表明，可以通过低成本喷雾热解技术制备大面积高质量CZTS膜，以实现基于CZTS的异质结太阳能电池的高产量商业生产。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号