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Optimal Filters for High-Speed Compressive Detection in Spectroscopy

机译:光谱中高速压缩检测的最佳滤波器

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Recent advances allow for the construction of filters with precisely defined frequency response for use in Raman chemical spectroscopy. In this paper we give a probabilistic interpretation of the output of such filters and use this to give an algorithm to design optimal filters to minimize the mean squared error in the estimated photon emission rates for multiple spectra. Experiments using these filters demonstrate that detecting as few as ~10 Raman scattered photons in as little time as ~30 μs can be sufficient to positively distinguish chemical species. This speed should allow "chemical imaging" of samples.
机译:最近的进展允许构造具有精确定义的频率响应的滤波器,以用于拉曼化学光谱中。在本文中,我们对此类滤波器的输出进行了概率解释,并以此为基础给出了一种算法,以设计最佳滤波器,以最小化多个光谱的估计光子发射速率中的均方误差。使用这些滤光片的实验表明,在短于约30μs的时间内检测到约10个拉曼散射光子就足以肯定地区分化学物质。该速度应允许样品的“化学成像”。

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