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Tortuosity of Binder-free and Carbon-free High Energy Density LiCoO_2 Electrodes for Rechargeable Lithium-ion Batteries

机译:可充锂离子电池用无粘合剂和无碳高能密度LiCoO_2电极的曲折度

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摘要

Conventional electrodes, by volume, contain a large amount of electrochemically inactive material such as binder and carbon. This lowers the overall capacity of a battery and makes it difficult to realize high volumetric energy. Researchers have been actively pursuing methods which will enable the fabrication and full utilization of thick electrodes (≥200μm) with a minimal amount of inactive material. One approach which has emerged is to fabricate thick sintered electrode structures which are free of binder and carbon. However, these structures do not adhere to conventional assumptions about tortuosity. This paper aims to correlate John Newman's macrohomogeneous porous electrode model to thick high energy density, carbon-free and binder-free sintered electrode samples fabricated at PARC. We examine how assumptions about tortuosity affect model predictions of capacity. Our efforts focus on understanding the model parameters which can be used in Newman's existing model without modification to the underlying equations.
机译:按体积计,常规电极包含大量电化学惰性材料,例如粘合剂和碳。这降低了电池的总容量,并且使得难以实现高体积能量。研究人员一直在积极地寻求能够制造和充分利用厚的电极(≥200μm)且使用最少的惰性材料的方法。已经出现的一种方法是制造没有粘合剂和碳的厚的烧结电极结构。但是,这些结构不符合有关曲折性的常规假设。本文旨在将John Newman的宏观均匀多孔电极模型与在PARC制造的厚的高能量密度,无碳和无粘结剂的烧结电极样品相关联。我们研究了关于曲折性的假设如何影响能力的模型预测。我们的工作重点是理解可以在不修改基础方程式的情况下在纽曼现有模型中使用的模型参数。

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  • 来源
  • 会议地点 San Francisco CA(US)
  • 作者

    C.L. Cobb; C.-J. Bae;

  • 作者单位

    Palo Alto Research Center (PARC), 3333 Coyote Hill Road, Palo Alto, CA, 94304 USA;

    Palo Alto Research Center (PARC), 3333 Coyote Hill Road, Palo Alto, CA, 94304 USA;

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  • 原文格式 PDF
  • 正文语种 eng
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