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Concentrated Solution Model of Transport in All Vanadium Redox Flow Battery Membrane Separator

机译:全钒氧化还原液流电池膜分离器中运输的集中解决方案模型

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摘要

A model of transport across the ion-exchange membrane in all-vanadium redox flow batteries has been proposed based on concentrated solution theory for species with high concentration. The model is based upon the Stefan-Maxwell multicomponent diffusion equation where the fluxes of the species including protons (H~+), bisulfate (HSO_4~-), water (H_2O) and the sulfonate functional groups (-SO_3~-) are fully coupled. The driving force for species transport has been modeled in terms of concentration and electrostatic potential gradients. The ionic transference numbers as well as water electro-osmosis drag coefficient has been calculated for different acid concentrations.
机译:基于浓溶液理论,针对高浓度物质提出了全钒氧化还原液流电池中跨离子交换膜的传输模型。该模型基于Stefan-Maxwell多组分扩散方程,其中质子(H〜+),硫酸氢盐(HSO_4〜-),水(H_2O)和磺酸盐官能团(-SO_3〜-)的通量完全耦合的。物种迁移的驱动力已根据浓度和静电势梯度进行了建模。对于不同的酸浓度,已经计算出离子转移数以及水的电渗透阻力系数。

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  • 会议地点 Orlando FL(US)
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    Electrochemical Energy Storage and Conversion Laboratory, Department of Mechanical, Aerospace and Biomedical Engineering, University of Tennessee, Knoxville, Tennessee 37996, USA;

    Chemical and Biomolecular Engineering Department, University of Tennessee, Knoxville, Tennessee 37996, USA,Physical Chemistry of Materials Group Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA;

    Electrochemical Energy Storage and Conversion Laboratory, Department of Mechanical, Aerospace and Biomedical Engineering, University of Tennessee, Knoxville, Tennessee 37996, USA,Energy and Transportation Science Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA;

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