首页> 外文会议>Conference on Active and passive smart structures and integrated systems; 20090309-12; San Diego, CA(US) >Electrospinning fabrication and electrochemical properties of lithium cobalt nanoflbers for lithium battery cathode
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Electrospinning fabrication and electrochemical properties of lithium cobalt nanoflbers for lithium battery cathode

机译:锂电池阴极锂钴纳米纤维的电纺丝制备及电化学性能

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In the present work, we have successfully fabricated nanostructured LiCoO_2 fibers using electrospinning technique from a viscous solution of lithium acetate/cobalt acetate/PVP (Polyvinylpyrrolidone), XRD (X-ray diffraction) and SEM (scanning electron microscopy) were performed to investigate the phase and microstructures of the electrospinning fibers respectively. Furthermore CV (cyclic voltammetry) and charge-discharge experiments were applied to characterize the electrochemical properties of LiCoO_2 nanoflbers. It is noteworthy that the nanostructured cathode offers a higher charge-discharge capacity compared with conventional powder or film cathodes, thus LiCoO_2 nanofiber cathode may become a promising candidate for the construction of microscale lithium ion batteries due to its larger surface to volume ratio.
机译:在目前的工作中,我们已经成功地使用静电纺丝技术从醋酸锂/醋酸钴/ PVP(聚乙烯吡咯烷酮)的粘性溶液,XRD(X射线衍射)和SEM(扫描电子显微镜)中制备了纳米结构的LiCoO_2纤维。纺丝纤维的相结构和微观结构。此外,通过CV(循环伏安法)和充放电实验来表征LiCoO_2纳米纤维的电化学性能。值得注意的是,与传统的粉末或薄膜阴极相比,纳米结构的阴极具有更高的充放电容量,因此,LiCoO_2纳米纤维阴极由于其较大的表面积与体积之比,可能成为制造微型锂离子电池的有前途的候选者。

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