首页> 外文会议>Conference on Laser Applications to Chemical and Environmental Analysis, Feb 11-13, 2000, Santa Fe, New Mexico >A Fourier Analysis Approach to Wavelength Modulation Diode Laser Absorption Spectrometry
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A Fourier Analysis Approach to Wavelength Modulation Diode Laser Absorption Spectrometry

机译:波长调制二极管激光吸收光谱的傅里叶分析方法

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A new theoretical formalism based on Fourier analysis that is capable of handling both analytical and background wavelength modulated signals under a variety of experimental situations has been developed. The new formalism has several appealing features; it is not restricted to small modulation amplitudes, it is capable of correctly predicting the influence of the associated intensity modulation (so called residual amplitude modulation, RAM, signals), it can deal with wavelength dependent transmission effects (e.g. etalon effects), it provides expressions for the analytical and background signals separately, and it elucidates clearly how the associated intensity and wavelength dependent transmission combine with the analyte absorption to form the total nf-harmonic signal at the lock-in amplifier output. Experimental verifications of both analytical and background signals are presented.
机译:基于傅立叶分析的一种新的理论形式主义已经能够在各种实验情况下处理分析和背景波长调制信号。新形式主义具有几个吸引人的特征。它不限于较小的调制幅度,它能够正确预测相关强度调制的影响(所谓的残余幅度调制,RAM,信号),它可以处理与波长有关的传输效应(例如,标准具效应),分别表示分析信号和背景信号的表达式,并清楚地说明了相关的强度和波长相关的传输如何与分析物的吸收相结合,从而在锁定放大器输出处形成总的nf谐波信号。提出了对分析信号和背景信号的实验验证。

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