Molecular quadratic nonlinear optical properties of dipolar ruthenium(Ⅱ) arsine complexes

机译：偶极钌（Ⅱ）a配合物的分子二次非线性光学性质

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A series of complex salts in which trans-bis[ 1,2-phenylenebis(dimethylarsine)]chlororuthenium(Ⅱ) electron donor groups are connected to pyridyl or pyridinium electron acceptors has been prepared. The chromophores in these compounds exhibit intense, visible metal-to-ligand charge-transfer (MLCT) absorptions and reversible Ru~( Ⅲ/Ⅱ) (and also in some cases ligand-based) redox processes. Stark (electroabsorption) spectroscopic studies have been used to determine dipole moment changes for the MLCT excitations. Static first hyperpolarizabilitiesβ_0 have been calculated according to the two-state model, allowing the derivation of structure-activity correlations for the molecular quadratic nonlinear optical responses.

机译：制备了一系列复杂的盐，其中反式-双[1,2-亚苯基双（二甲基ar）]氯钌（Ⅱ）电子供体基团连接到吡啶基或吡啶鎓电子受体上。这些化合物中的发色团表现出强烈的可见金属-配体电荷转移（MLCT）吸收和可逆的Ru〜（Ⅲ/Ⅱ）（在某些情况下还基于配体）的氧化还原过程。斯塔克（电吸收）光谱研究已用于确定MLCT激发的偶极矩变化。根据二态模型计算出静态的第一超极化率β_0，从而可以推导分子二次非线性光学响应的结构活性相关性。

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《Conference on Linear and Nonlinear Optics of Organic Materials III; Aug 4-6, 2003; San Diego, California, USA》|2003年|p.332-340|共9页
会议地点 San Diego CA(US)
作者
Josephine L. Harries; Benjamin J. Coe; James A. Harris; Bruce S. Brunschwig;
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作者单位

Department of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
ruthenium complexes; pyridinium salts; stark spectroscopy;

机译：钌配合物；吡啶盐；斯塔克光谱;

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专利

1. Syntheses, spectroscopic and molecular quadratic nonlinear optical properties of dipolar ruthenium(II) complexes of the ligand 1,2-phenylenebis(dimethylarsine) [J] . Coe BJ, Harries JL, Harris JA, Dalton transactions: An international journal of inorganic chemistry . 2004,第18期

机译：1,2-亚苯基双（二甲基ar）的偶极钌（II）配合物的合成，光谱和分子二次非线性光学性质
2. A spectroscopic, electrochemical and structural study of polarizable, dipolar ruthenium(II) arsine complexes as models for chromophores with large quadratic non-linear optical responses [J] . Coe BJ., Jeffery JC., Coles SJ., Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第5期

机译：可极化的偶极钌（II）rs络合物作为具有大的二次非线性光学响应的生色团的模型的光谱，电化学和结构研究
3. Syntheses and Spectroscopic and Quadratic Nonlinear Optical Properties of Extended Dipolar Complexes with Ruthenium(II) Ammine Electron Donor and N-Methylpyridinium Acceptor Groups [J] . Benjamin J. Coe, Lathe A. Jones, James A. Harris, Journal of the American Chemical Society . 2004,第12期

机译：带有钌（II）胺电子给体和N-甲基吡啶受体基团的扩展偶极配合物的合成，光谱和二次非线性光学性质
4. Molecular quadratic nonlinear optical properties of dipolar ruthenium(II) arsine complexes [C] . Josephine L. Harries, Benjamin J. Coe, James A. Harris, Conference on linear and nonlinear optics of organic materials . 2003

机译：偶极钌（II）胂配合物的分子二次非线性光学性质
5. Synthesis of selected electron donors and acceptors and study of inter/intramolecular electron transfer from ruthenium(II) complexes in solution, frozen matrix and silica aerogels as the basis for optical devices. [D] . Rawashdeh, Abdel Monem M. 2003

机译：选择性电子供体和受体的合成以及溶液，冷冻基质和二氧化硅气凝胶中钌（II）配合物作为光学器件基础的分子间/分子间电子转移的研究。
6. Optical Properties of Isolated and Covalent OrganicFramework-Embedded Ruthenium Complexes [O] . Francesco Muniz-Miranda, ⊥, ∥, -1

机译：分离的共价有机物的光学性质框架嵌入钌配合物
7. Syntheses, spectroscopic and molecular quadratic nonlinear optical properties of dipolar ruthenium(II) complexes of the ligand 1,2-phenylenebis(dimethylarsine) [O] . Coe, Benjamin J., Harries, Josephine L., Harris, James A., 2004

机译：配体1,2-亚苯基双（二甲基胂）的偶极钌（II）配合物的合成，光谱和分子二次非线性光学性质

Molecular quadratic nonlinear optical properties of dipolar ruthenium(Ⅱ) arsine complexes

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