Controllable far infrared transmitting glass-ceramics based on chalcogenide and halide

机译：基于硫族化物和卤化物的可控远红外透射微晶玻璃

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New infrared transmitting glass ceramics based on the Ge-Sb-S-CsCl system have been studied. By selecting an appropriate glass composition, glass ceramics with different quantities of micro-crystals can be reproducibly obtained with different annealing temperatures and durations. The presence of crystals induces some additional losses in the short wavelength region, namely between 0.6 and 2 μm. However, the glass ceramics keep the same transmission as the original glass after 3 μm up to 11 μm. To our best knowledge, it is the first time that highly reproducible glass-ceramics based on chalcogenide glasses are obtained. Compared to the glass, the corresponding glass-ceramics show better resistance to fracture propagation. The feasibility of shaping the glass-ceramics by molding has also been demonstrated.

机译：研究了基于Ge-Sb-S-CsCl体系的新型红外透射玻璃陶瓷。通过选择合适的玻璃组成，可以以不同的退火温度和持续时间可再现地获得具有不同数量的微晶的玻璃陶瓷。晶体的存在会在短波长区域（即0.6至2μm之间）引起一些额外的损耗。但是，玻璃陶瓷在3μm至11μm后仍保持与原始玻璃相同的透射率。据我们所知，这是首次获得基于硫属化物玻璃的高重现性玻璃陶瓷。与玻璃相比，相应的玻璃陶瓷具有更好的抗断裂扩展性。还已经证明了通过模制使玻璃陶瓷成形的可行性。

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来源
《Conference on Optical Components and Materials; 20040126-20040127; San Jose,CA; US》|2004年|P.123-131|共9页
会议地点 San Jose CA(US)
作者
Xianghua ZHANG; Hongli MA; Jacques LUCAS;
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作者单位

UMR CNRS 6512 "Verres et Ceramiques", Institut de Chimie, Universite de Rennes I, Bat. 10 A, Campus de Beaulieu, 35042 Rennes cedex, France;

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会议组织
原文格式 PDF
正文语种 eng
中图分类 TB342;
关键词
IR transmission; glass-ceramics; chalcogenide; halide; mechanical properties;

机译：红外透射;玻璃陶瓷;硫族化物;卤化物;力学性能;

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专利

1. A new class of infrared transmitting glass-ceramics based on controlled nucleation and growth of alkali halide in a sulphide based glass matrix [J] . Zhang XH, Hongli MA, Lucas J Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2004,第2期

机译：基于碱金属卤化物在硫化物基玻璃基质中的受控成核和生长的新型红外透射玻璃陶瓷
2. Phase Separation Inducing Controlled Crystallization of GeSe_2-Ga_2Se_3-CsI Glasses for Fabricating Infrared Transmitting Glass-Ceramics [J] . Cunming Liu, Gao Tang, Lan Luo, Journal of the American Ceramic Society . 2009,第1期

机译：用于制造红外透射玻璃陶瓷的GeSe_2-Ga_2Se_3-CsI玻璃的相分离诱导控制结晶
3. Controlled crystallization of GeS2-Sb2S3-CsCl glass for fabricating infrared transmitting glass-ceramics [J] . Zhu SZ, Ma HL, Matecki M, Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites . 2005,第40a42期

机译：用于制造红外透射玻璃陶瓷的GeS2-Sb2S3-CsCl玻璃的可控结晶
4. Controllable far infrared transmitting glass-ceramics based on chalcogenide and halide [C] . Xianghua ZHANG, Hongli MA, Jacques LUCAS, Conference on optical components and materials . 2004

机译：基于硫属化物和卤化物的可控远红外传输玻璃陶瓷
5. Fabrication of low-loss infrared-transmitting chalcogenide optical fibers. [D] . Nguyen, Vinh Quang. 1999

机译：低损耗红外透射硫族化物光纤的制造。
6. Unravelling interrelations between chemical composition and refractive index dispersion of infrared-transmitting chalcogenide glasses [O] . Jun Ho Lee, Ju Hyeon Choi, Jeong Han Yi, -1

机译：揭示硫族化物玻璃的化学成分与折射率色散之间的相互关系
7. Chalcogenide glasses and glass-ceramics: Transparent materials in the infrared for dual applications [O] . Calvez, Laurent 2017

机译：硫属化物玻璃和玻璃陶瓷：红外透明材料可双重用途
8. Titanium Chalcogenide Infrared Transmitting Glasses [R] . Hilton, A. R. 1967

机译：钛硫属化物红外透射玻璃

Controllable far infrared transmitting glass-ceramics based on chalcogenide and halide

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