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Characterization of Poly (vinyl chloride)/Bentonite Nanocomposite Prepared via Melt Blending Method

机译:熔融共混法制备的聚氯乙烯/膨润土纳米复合材料的表征

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摘要

Poly(vinyl chloride) based nanocomposites were prepared by blending with organically modified bentonite particles at three different temperatures 160℃, 170℃, 180℃ to compare the temperature effect on the morphology of the composites. The unmodified bentonite was also used as the filler material to prepare poly(vinyl chloride)/unmodified bentonite for comparison. The thermal properties of the samples prepared in this work were examined by differential scanning calorimetery and thermal gravimetric analysis. The results of differential scanning calorimetery showed the existence of the single glass transition temperature for all compositions and in comparison with pristine poly(vinyl chloride) the composites made out to be higher glass transition temperatures. The thermal degradation temperature of the composites also increased up to 60℃ in comparison with pristine poly(vinyl chloride). The dispersion and interfacial compatibility of bentonite in poly(vinyl chloride) matrix was characterized by scanning electron microscope.
机译:通过与有机改性的膨润土颗粒在160℃,170℃,180℃这三种不同温度下混合,制备了聚氯乙烯基纳米复合材料,以比较温度对复合材料形态的影响。未改性的膨润土也被用作填充材料以制备聚(氯乙烯)/未改性的膨润土用于比较。通过差示扫描量热法和热重分析法检查了在这项工作中制备的样品的热性质。差示扫描量热法的结果表明,所有组合物都存在单一的玻璃化转变温度,并且与原始的聚氯乙烯相比,该复合材料具有更高的玻璃化转变温度。与原始聚氯乙烯相比,复合材料的热降解温度也提高了60℃。用扫描电子显微镜对膨润土在聚氯乙烯中的分散性和界面相容性进行了表征。

著录项

  • 来源
  • 会议地点 Valletta(MT)
  • 作者单位

    Department of Chemistry, Engineering Faculty, University of Istanbul,34320 Avcilar-lstanbul, Turkey;

    Faculty of Technology, University of Novi Sad, Serbia;

    Department of Polymer Science and Engineering, University of Massachusetts, Amherst, MA 01002, USA;

    Department of Chemistry, Engineering Faculty, University of Istanbul,34320 Avcilar-lstanbul, Turkey;

  • 会议组织
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 TQ050.43;
  • 关键词

  • 入库时间 2022-08-26 14:19:56

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