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Controlled radical polymerizations as versatile synthetic routes for conjugated rod-coil block copolymers and their use as active polymer semiconducting materials in flexible organic electronic devices and systems

机译：受控自由基聚合作为共轭棒-线圈嵌段共聚物的通用合成路线，并在柔性有机电子器件和系统中用作活性聚合物半导体材料

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Controlled Radical Polymerization (CRP) such as Atom Transfer Radical Polymerization (ATRP) or Nitroxide Mediated Radical Polymerization (NMRP), can be used to obtain various well defined rod-coil conjugated diblock or triblock copolymers having well controlled opto-electronic properties. These copolymers are soluble in common organic solvents and can be self-organized giving rise at various nm length scale and thermodynamically stable structures. They show promising opto-electronic properties and fulfil the basic morphological requirements towards the fabrication of efficient flexible organic electronic devices.

机译：受控的自由基聚合（CRP），例如原子转移自由基聚合（ATRP）或一氧化氮介导的自由基聚合（NMRP），可用于获得具有良好受控的光电性能的各种定义明确的棒-线圈共轭二嵌段或三嵌段共聚物。这些共聚物可溶于常见的有机溶剂，并且可以自组织，从而在各种nm长度范围内产生并具有热力学稳定的结构。它们显示出有前途的光电特性，并满足制造高效柔性有机电子器件的基本形态要求。

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《Controlled/living radical polymerization: Progress in ATRP》|2008年|243-256|共14页
会议地点 Philadelphia PA(US)
作者
Cyril Brochon; Georges Hadziioannou;
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Laboratoire d'Ingenierie des Polymeres pour les Hautes Technologies Universite de Strasbourg Ecole Europeenne de Chimie, Polymeres et Materiaux (ECPM) 25 rue Becquerel 67087 Strasbourg, France;

Laboratoire d'Ingenierie des Polymeres pour les Hautes Technologies Universite de Strasbourg Ecole Europeenne de Chimie, Polymeres et Materiaux (ECPM) 25 rue Becquerel 67087 Strasbourg, France;

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1. Controlled radical polymerizations as versatile synthetic routes for conjugated rod-coil block copolymers and their use as active polymer semiconducting materials in flexible organic electronic devices and systems [J] . Cyril Brochon, Georges Hadziioannou ACS Symposium Series . 2009,第Null期

机译：受控自由基聚合作为共轭棒-线圈嵌段共聚物的通用合成路线，并在柔性有机电子器件和系统中用作活性聚合物半导体材料
2. Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis [J] . Federico Di Sacco, Andrea Pucci, Patrizio Raffa Nanomaterials . 2019,第3期

机译：通过原子转移自由基聚合和合成后修饰制成的多功能嵌段共聚物：从挥发性有机化合物传感器转换为用于通过水解控制水流变性的聚合物表面活性剂
3. Synthesis of Poly(paraphenylene vinylene)-Polystyrene-Based Rod-Coil Block Copolymer by Atom Transfer Radical Polymerization: Toward a Self-Organized Lamellar Semiconducting Material [J] . Brochon C, Sary N, Mezzenga R, Journal of Applied Polymer Science . 2008,第6期

机译：原子转移自由基聚合合成聚对苯乙炔-聚苯乙烯基棒状嵌段共聚物：一种自组织的层状半导体材料
4. Controlled radical polymerizations as versatile synthetic routes for conjugated rod-coil block copolymers and their use as active polymer semiconducting materials in flexible organic electronic devices and systems [C] . Cyril Brochon, Georges Hadziioannou ACS symposium on controlled/living radical polymerization . 2009

机译：控制自由基聚合作为共轭杆线圈嵌段共聚物的通用合成途径，它们用作柔性有机电子设备和系统中的活性聚合物半导体材料
5. Controlled self-assembly of conjugated rod-coil block copolymers for applications in organic optoelectronics. [D] . Tao, Yuefei. 2008

机译：共轭棒-线圈嵌段共聚物的可控自组装，可用于有机光电。
6. Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis [O] . Federico Di Sacco, Andrea Pucci, Patrizio Raffa 2019

机译：通过原子转移自由基聚合和合成后修饰制成的多功能嵌段共聚物：从挥发性有机化合物传感器转换为用于通过水解控制水流变性的聚合物表面活性剂
7. Versatile Multi-Functional Block Copolymers Made by Atom Transfer Radical Polymerization and Post-Synthetic Modification: Switching from Volatile Organic Compound Sensors to Polymeric Surfactants for Water Rheology Control via Hydrolysis [O] . Federico Di Sacco, Andrea Pucci, Patrizio Raffa 2019

机译：由原子转移自由基聚合和合成后改性的多功能多功能嵌段共聚物：通过水解从挥发性有机化合物传感器切换到聚合物表面活性剂的聚合物表面活性剂
8. Versatile Route to Functionalized Block Copolymers by Nitroxide Mediated 'Living' Free Radical Polymerization [R] . Benoit, D. , Rivera, F. J. , Piotti, M. , 1999

机译：通过氮氧化物介导的“活性”自由基聚合的功能化嵌段共聚物的通用途径

Controlled radical polymerizations as versatile synthetic routes for conjugated rod-coil block copolymers and their use as active polymer semiconducting materials in flexible organic electronic devices and systems

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