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Temperature-dependent luminescence and energy transfer in Europium and rare-earth-codoped nanostructured sol-gel SiO2 glasses

机译:Euro和稀土掺杂纳米结构溶胶凝胶SiO2玻璃的温度依赖性发光和能量转移

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Abstract: Temperature-dependent luminescence spectra, lifetimes and energy transfer in Eu$+3$PLU$/ and other rare earths co- doped sol-gel SiO$-2$/ glasses, were investigated in the temperature range from 10K to 300K. Due to the addition of the other rare earths as co-dopants, luminescence spectra of Eu$+3$PLU$/ have shown significant changes not only in spectral intensities but also in emission peak features. Evaluation of the temperature-dependent energy transfer rates and lifetimes and the computation of critical energy transfer distances by employing two different energy transfer model schemes, have provided evidence for such luminescence behavior in the nanometer-size confined glass matrices. !16
机译:摘要:在10K至300K的温度范围内,研究了Eu $ + 3 $ PLU $ /和其他稀土共掺杂的溶胶-凝胶SiO $ -2 $ /玻璃中随温度变化的发光光谱,寿命和能量转移。由于添加了其他稀土元素作为共掺杂剂,Eu $ + 3 $ PLU $ /的发光光谱不仅在光谱强度上而且在发射峰特征上均显示出显着变化。通过使用两种不同的能量传递模型方案评估与温度相关的能量传递速率和寿命,以及计算临界能量传递距离,为纳米尺寸的受限玻璃基质中的这种发光行为提供了证据。 !16

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