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IN SITU CARBOTHERMAL REDUCTION/NITRIDATION CARBON-NANO POWDER ADDED GEOPOLYMER COMPOSITES

机译:原位碳热还原/硝化碳-纳米粉添加地聚合物复合材料

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摘要

Geopolymer was prepared by mixing metakaolin (Al_2O_3.SiO_2) with sodium water glass solution and then the activated carbon nano powder was added the geopolymer. To determine the best composition for carbothermal reduction, one series geoploymer was made with and without carbon by hand. The viscous and homogenous slurry was poured into a mold to obtain bar samples at ambient temperature and cured in a humidity-controlled, constant temperature oven at 50 ℃ for 24 h. The composition of Na_2O•Al_2O_3•4.5SiO_2•12H_2O+9C was determined to be best for carbothermal reduction. The carbothermal reduction process of the samples were carried out in an atmosphere controlled tube furnace both under argon (denoted as CTR) and nitrogen (denoted as CTRN) flow of 5 cm~3.min~(-1) at temperatures varying between 1450-1550 ℃ for 2h. XRD and SEM analyses were used to determine in situ transformation and morphology of all the products after CTR and CTRN. The results were briefly discussed with respect to possibility of in situ conversion of geopolymers to its carbide and nitride analogues.
机译:通过将偏高岭土(Al_2O_3.SiO_2)与钠水玻璃溶液混合来制备地质聚合物,然后将活性炭纳米粉末添加到该地质聚合物中。为了确定用于碳热还原的最佳成分,手工制作了一种含碳和不含碳的系列地质聚合物。将粘稠的均质浆液倒入模具中,以在环境温度下获得条形样品,并在湿度控制的恒温烤箱中于50℃固化24小时。 Na_2O·Al_2O_3·4.5SiO_2·12H_2O + 9C的组成被确定为最适合碳热还原的元素。样品的碳热还原过程是在气氛控制的管式炉中进行的,其中氩气(表示CTR)和氮气(表示CTRN)在5 cm〜3.min〜(-1)的流量下于1450- 1550℃下2h。 XRD和SEM分析用于确定CTR和CTRN之后所有产品的原位转化和形态。关于将地质聚合物原位转化为其碳化物和氮化物类似物的可能性,简要讨论了结果。

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  • 会议地点 Daytona Beach FL(US)
  • 作者单位

    Department of Metallurgical and Materials Engineering, Faculty of Engineering, Hitit University, Corum, 19030, TURKEY;

    Department of Material Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL, 61801, USA;

    Department of Material Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL, 61801, USA;

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