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Light-Emitting and Hole-Transporting Polymers for LEDs

机译:LED的发光和空穴传输聚合物

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Various copolymers of arylene vinylenes, having strong fluorescence, showed predominantly the emission in the multi-layer device using an electron-transporting material(ETM) such as tris(8-quinolinolato)aluminum(Alq_3). The emission from Alq_3 was suppressed due to the high hole-injection barrier from the copolymers to ETM in spite of low or no barriers of electron injection from ETM to the copolymers.rnWe have successfully prepared highly hole-transporting polysilane having a triphenylamine group as a side chain(TPA-PS). The hole mobility as high as 10~3cm~2/Vs is attributable to the intermolecular hopping process facilitated by the interaction between the polysilane backbone and the triphenylamine group. The polysilane is effectively used as a hole transporting material. The bilayer LED device consisting of TPA-PS and Alq_3 showed high luminance (2000cd/m~2) and high efficiency (4cd/A).
机译:具有强荧光的亚芳基亚乙烯基的各种共聚物在使用电子传输材料(ETM)(例如三(8-喹啉基)铝(Alq_3))的多层器件中主要显示出发射。尽管从ETM到共聚物的电子注入势垒很小或没有障碍,但由于从共聚物到ETM的空穴注入势垒很高,Alq_3的发射得到了抑制。我们已经成功地制备了具有三苯胺基团的高空穴传输性聚硅烷。侧链(TPA-PS)。空穴迁移率高达10〜3cm〜2 / Vs归因于聚硅烷骨架与三苯胺基团之间的相互作用促进了分子间跳跃过程。聚硅烷有效地用作空穴传输材料。由TPA-PS和Alq_3组成的双层LED器件显示出高亮度(2000cd / m〜2)和高效率(4cd / A)。

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