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Controlled Interfacial Synthesis of MnO_2 and its Application in Supercapacitors

机译:MnO_2的受控界面合成及其在超级电容器中的应用

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A controlled interfacial synthesis has been used to obtain ε - MnO_2 of varying surface area between 50 and 160 m~2 g~(-1) and pore volumes between 0.3 and 0.4 cm~3 g~(-1). The synthesis conditions have been shown to have a marked effect on pore size distributions. These materials have been cast into composite electrode films. The differences in pore size and surface areas of the films are compared to those of the precursor powders. After assembly in supercapacitor test cells with aqueous neutral electrolyte, Specific capacitances have been assessed through galvanostatic cycling giving initial values as high as 448 F g~(-1), dropping to 260 F g~(-1) after 5 cycles but showing no further degradation over 200 cycles.
机译:受控的界面合成已被用于获得在50和160 m〜2 g〜(-1)之间变化的表面积和在0.3和0.4 cm〜3 g〜(-1)之间的孔体积的ε-MnO_2。已经表明合成条件对孔径分布具有显着影响。这些材料已浇铸成复合电极膜。将膜的孔径和表面积的差异与前体粉末的孔径和表面积的差异进行比较。在将中性电解质水溶液装入超级电容器测试电池中后,通过恒电流循环对比电容进行了评估,其初始值高达448 F g〜(-1),5个循环后降至260 F g〜(-1),但未显示出在200个周期内进一步退化。

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