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Nanocomposites for Water Treatment - Maghemite as a photocatalyst

机译:用于水处理的纳米复合材料-磁赤铁矿作为光催化剂

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摘要

The treatment of waste water involves, amongst other processes, the removal of heavy metal ion pollutants and/or organic contaminants. As one component of a potential aluminosilicate nanocomposite for water treatment, we have demonstrated the effectiveness of using Maghemite (γ-Fe_2O_3) as a photocatalyst for the reduction of the aqueous pollutant chromium(Ⅵ) to chromium(Ⅲ) in the presence of a sacrificial organic reductant. Maghemite has the twin advantages of being a photocatalyst that exhibits strong absorbance in the visible region of the spectrum and of being magnetic, so facilitating post processing solid/liquid separation. During this study, a simple, robust, calibrationless potentiometric technique for monitoring the concentration of chromium(Ⅵ) was developed. This method allowed the photocatalytic reduction of Cr(Ⅵ) to be observed in real-time with no sample pre-treatment.
机译:除其他过程外,废水的处理还包括去除重金属离子污染物和/或有机污染物。作为潜在的水处理硅铝酸盐纳米复合材料的一种组分,我们已经证明了在牺牲性存在下,使用磁赤铁矿(γ-Fe_2O_3)作为光催化剂将水污染物中的铬(Ⅵ)还原为铬(Ⅲ)的有效性。有机还原剂。磁赤铁矿具有双重优势:作为光催化剂,在光谱的可见光区域具有强吸收性,并且具有磁性,因此便于后处理过程中的固/液分离。在这项研究中,开发了一种简单,可靠,无需校准的电位计技术,用于监测铬(Ⅵ)的浓度。该方法无需进行样品预处理即可实时观察到光催化还原Cr(Ⅵ)。

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