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Development of layer-by-layer CNT thin film assemblies for volatile organic compounds sensing

机译:用于挥发性有机化合物传感的逐层CNT薄膜组件的开发

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In this study carbon nanotubes (CNT)-based conductive polymer nanocomposites fabricated by electrostatic layerby-layer (LbL) technique were used as the sensitive gas sensors. The conductive layers were progressively built alternative exposing into sodium deoxycholate (DOC)stabilized CNT anionic and poly(diallyldimethyl-ammonium chloride) [PDDA] cationic solutions, respectively. By this technique the fine control of sensitivity to VOC was accomplished due to a fine tuning of multilayer films resistance (from 50 to 2 kΩ) by the precise control of layer thicknesses (from 5 to 40 nm). This study resulted that 16 bilayer PDDA/(CNT+DOC) LbL assemblies provided the optimum detecting and diagnosing performances of eight VOC vapors (i.e., chloroform, acetone, ethanol, water, toluene, dichloromethane, tetrahydrofuran and methanol).
机译:在这项研究中,通过静电逐层(LbL)技术制造的基于碳纳米管(CNT)的导电聚合物纳米复合材料用作敏感的气体传感器。逐步构建导电层,分别暴露于脱氧胆酸钠(DOC)稳定的CNT阴离子和聚二烯丙基二甲基氯化铵[PDDA]阳离子溶液中。通过精确控制层厚度(5至40 nm),通过对多层膜电阻(50至2kΩ)进行微调,可以实现对VOC灵敏度的精细控制。这项研究的结果是16个双层PDDA /(CNT + DOC)LbL组件提供了8种VOC蒸气(即氯仿,丙酮,乙醇,水,甲苯,二氯甲烷,四氢呋喃和甲醇)的最佳检测和诊断性能。

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