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Cerium(iv) phosphate: characterisation and intercalation of amines

机译:磷酸铈(iv):胺的表征和嵌入

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摘要

Using previously reported methods several cerium(IV) phosphates (CePs) were prepared. On the basis of elemental analysis, PXRD, TGA, IR and amine uptake, we conclude that for those phosphates for which P/Ce approx 2 there are at least two layered structures, neither of which is isostructural with the wel-known alpha - or gamma - M(IV) phosphate structures. A structure with P/Ceapprox1.5 also appears to be layered. Powder X-ray measurements minitoring amine uptake by the phosphates are also reported.
机译:使用先前报道的方法,制备了几种磷酸铈(IV)。根据元素分析,PXRD,TGA,IR和胺吸收,我们得出结论,对于P / Ce约为2的那些磷酸盐,至少有两个层状结构,它们都不是同构的,具有众所周知的α-或γ-M(IV)磷酸盐结构。 P / Ceapprox1.5的结构也似乎是分层的。还报道了粉末X射线测量方法,可减少磷酸盐吸收胺。

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