ELECTROCHEMISTRY IN IONIC LIQUIDS. VOLTAMMETRY AND ELECTROCHEMICAL REDUCTION OF DINITRO COMPOUNDS

机译：离子液体中的电化学。 DINITRO化合物的伏安法和电化学还原

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1-Alkyl-3-methylimidazolium tetrafluoroborates (1) have been investigated as electrochemical solvents. Cyclic voltammograms of nitrobenzene and the three isomeric dinitrobenzenes in acetonitrile and 1 demonstrate unprecedentedly strong ion-pairing effects on the corresponding dinitro dianions in 1. All four nitro compounds underwent electrochemical reductive acetylation in good yield in 1 containing acetic anhydride. These are the first reported preparative electrolyses in ionic liquids. The viscosity of liquids 1 leads to lower diffusion coefficients (by factors of 200 or more) indicating that these media are not well suited for electroanalytical methods requiring high sensitivity.

机译：已经研究了1-烷基-3-甲基咪唑鎓四氟硼酸盐（1）作为电化学溶剂。乙腈和1中的硝基苯和三种异构二硝基苯的循环伏安图显示，其对1中相应的二硝基阴离子具有空前强大的离子配对作用。所有四种硝基化合物均在1种含乙酸酐中进行了电化学还原乙酰化，收率很高。这些是在离子液体中首次报道的制备性电解。液体1的粘度导致较低的扩散系数（系数为200或更大），表明这些介质不适用于要求高灵敏度的电分析方法。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.77-80|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Albert J. Fry; Dennis G. Peters;
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Department of Chemistry, Wesleyan University, Middletawn, CT 06459, U.S.A.;

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原文格式 PDF
正文语种 eng
中图分类化学;
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2. Electrochemistry and Raman spectroscopy of niobium reduction in basic and acidic pyrrolidinium based ionic liquids. Part I: 1-Butyl-1-methylpyrrolidinium chloride with NbCl_5 [J] . Olga B. Babushkina, Eugenia O. Lomako, Werner Freyland Electrochimica Acta . 2012,第Null期

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4. Electrochemistry in ionic liquids. Voltammetry and electrochemical reduction of dinitro compounds [C] . Albert J Fry, Dennis G. Peters International Manuel M. Baizer Symposium . 2002

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5. The electrochemistry and spectroelectrochemistry of rhenium chloride cluster compounds in aluminum chloride-1-methyl-3-ethylimidazolium chloride room-temperature ionic liquids. [D] . Strubinger, Sandra K. D. 1990

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ELECTROCHEMISTRY IN IONIC LIQUIDS. VOLTAMMETRY AND ELECTROCHEMICAL REDUCTION OF DINITRO COMPOUNDS

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