ELECTROCHEMICALLY-INDUCED REACTIVITY OF FULLERENE DERIVATIVES

机译：富勒烯衍生物的电化学诱导反应性

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A series of bis(alkoxycarbonyl)methanofullerene derivatives, carrying crown ethers moieties, were investigated by cyclic voltammetry under strictly aprotic conditions. The electrochemical study evidenced the occurrence of fast reactions following the injection of either three (at 25℃) or four (at -60 ℃) electrons. Such a reaction was, however, fully reversed upon reoxidation of the species in the reverse scan.

机译：在严格的非质子条件下，通过循环伏安法研究了一系列带有冠醚部分的双（烷氧羰基）亚甲基富勒烯衍生物。电化学研究表明，注入三个（25℃）或四个（-60℃）电子后会发生快速反应。然而，当在反向扫描中物质再氧化时，这种反应被完全逆转。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.73-76|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Maurizio Carano; Luigi Garlaschelli; Michele Maggini; Massimo Marcaccio; Demis Paolucci; Francesco Paolucci; Sergio Roffia;
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University of Bologna, Department of Chemistry, via Selmi 2, 40126 Bologna, Italy;

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原文格式 PDF
正文语种 eng
中图分类化学;
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专利

1. Mechanisms of electrochemically-induced retro-cyclopropanation reactions of fullerene derivatives using digital simulations [J] . Maurizio Carano, Luis Echegoyen Chemistry: A European journal . 2003,第9期

机译：富勒烯衍生物电化学诱导的逆向丙烷丙烷化反应机理的数字模拟
2. The chemical reactivity of fullerene C-60 towards fac-Mo(CO)(3) (MeCN)(dppe) and Mo(CO)(4)(dppe). Synthesis, characterization and reactions of the novel fullerene molybdenum derivative fac-Mo(CO)(3)(dppe)(eta(2)-C-60) [J] . Song LC., Hu QM., Zhu YH. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1998,第4期

机译：富勒烯C-60对fac-Mo（CO）（3）（MeCN）（dppe）和Mo（CO）（4）（dppe）的化学反应性。新型富勒烯钼衍生物fac-Mo（CO）（3）（dppe）（eta（2）-C-60）的合成，表征和反应
3. Voltammetric characterization of C-60(PhX)(2) (X = H, Br) and digital simulation of their electrochemically-induced reactivity [J] . Carano M, Marcaccio M, Paolucci F, Photochemical & photobiological sciences: the official journal of the European Photochemistry Association and the European Society for Photobiology . 2006,第12期

机译：C-60（PhX）（2）（X = H，Br）的伏安法表征及其电化学诱导反应性的数字模拟
4. Electrochemically-induced reactivity of fullerene derivatives [C] . Maurizio Carano, Luigi Garlaschelli, Michele Maggini, International Manuel M. Baizer Symposium . 2002

机译：富勒烯衍生物的电化学诱导的反应性
5. Crystallographic Structural Studies of Various Inorganic Compounds, Fullerene Derivatives, and Fullerene Cocrystals [D] . Claire, Faye Louisa 2013

机译：各种无机化合物，富勒烯衍生物和富勒烯共晶体的晶体学结构研究
6. Antioxidant Properties of Fullerene Derivatives Depend on Their Chemical Structure: A Study of Two Fullerene Derivatives on HELFs [O] . Vasilina Sergeeva, Olga Kraevaya, Elizaveta Ershova, 2019

机译：富勒烯衍生物的抗氧化性能取决于其化学结构：两种HEF上的富勒烯衍生物的研究
7. Reactions of Fullerenes with Reactive Methylene Organophosphorus Reagents: Efficient Synthesis of Organophosphorus Group Substituted C60 and C70 Derivatives [O] . -1

机译：富勒烯与反应性甲基有机磷试剂的反应：有效合成有机磷基团取代的C60和C70衍生物

ELECTROCHEMICALLY-INDUCED REACTIVITY OF FULLERENE DERIVATIVES

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