THE USE OF SOLID METALLIC CATHODES IN ORGANIC ELECTROCHEMISTRY. IMMOBILIZATION OF π-ACCEPTORS ONTO PLATINUM INTERFACES

机译：固体金属阴极在有机电化学中的使用。 π受体在白金界面上的固定化

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The metal/electrolyte reduced phases generally of stoichiometry (Pt_2~-, 2M~+, X~-) cathodically formed at the platinum interface in the presence of electrolyte MX, may unexpectedly react with π-acceptors. Such an immobilization of aromatic ketones and their reduced forms has been shown by coulometry and EQCM analysis and the stoichiometry of transients under electrolysis was determined. This temporary immobilization at the platinum interface of reduced forms of aromatic ketones could be seen as an encapsulation and then orientate coupling regioselectivity.

机译：在电解质MX存在下在铂界面上阴极形成的通常化学计量的金属/电解质还原相（Pt_2〜-，2M〜+，X〜-）可能意外地与π受体反应。库仑法和EQCM分析已显示出芳族酮及其还原形式的固定化，并测定了电解下的瞬态化学计量。还原形式的芳族酮在铂界面上的这种暂时固定可以看作是包封，然后定向偶合区域选择性。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.40-43|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Charles Cougnon; Jacques Simonet;
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Laboratoire d'Electrochimie ― UMR 6510 ― Campus de Beaulieu ― University de Rennes, 35042 Rennes Cedex (France);

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正文语种 eng
中图分类化学;
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1. Cathodic immobilization of π-acceptors such as aromatic ketones onto platinum interfaces under superdry conditions [J] . Charles Cougnon, Jacques Simonet Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry . 2002,第2期

机译：在超干条件下将π受体（如芳香族酮）阴极固定在铂界面上
2. Taming Active Material-Solid Electrolyte Interfaces with Organic Cathode for All-Solid-State Batteries [J] . Fang Hao, Xiaowei Chi, Yanliang Liang, Joule . 2019,第5期

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3. 9-Fluorenyl radical: Electrochemical generation and cathodic immobilization at solid interfaces [J] . Simonet J., Jouikov V. Electrochemistry communications . 2011,第3期

机译：9-芴基：固体界面的电化学产生和阴极固定
4. The use of solid metallic cathodes in organic electrochemistry. Immobilization of π-acceptors onto platinum interfaces [C] . Charles Cougnon, Jacques Simonet International Manuel M. Baizer Symposium . 2002

机译：用固体金属阴极在有机电化学中的应用。将π-受体固定到铂界面上
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THE USE OF SOLID METALLIC CATHODES IN ORGANIC ELECTROCHEMISTRY. IMMOBILIZATION OF π-ACCEPTORS ONTO PLATINUM INTERFACES

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