OPTIMIZING TURNOVER OF A METALLOPOLYION-COATED ELECTRODE IN A FLOW CELL IN MICROEMULSIONS

机译：微乳液中流动池中金属离子包覆电极的最优化周转

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Covalently bound Vitamin B12 hexacarboxylic acid [B_(12)(COOH)_6]-poly(L-lysine) [PLL] on graphite electrodes was evaluated for green electrochemical synthesis in a flow cell in microemulsions. Improved film formation procedure gave higher and more active catalyst surface concentration compared to an earlier method. A parallel plate flow reactor containing a catalyst-coated carbon cloth cathode gave 6-fold larger turnover rates compared to a stirred batch reactor, and maintained 100% current efficiency for catalytic conversion of trans-1,2-dibromocyclohexane [DBCH] to cyclohexene.

机译：评价了在石墨电极上共价键合的维生素B12六羧酸[B_（12）（COOH）_6]-聚（L-赖氨酸）[PLL]在微乳液中在流通池中的绿色电化学合成。与较早的方法相比，改进的成膜程序可提供更高和更多的活性催化剂表面浓度。与搅拌的间歇式反应器相比，包含催化剂涂覆的碳布阴极的平行板流反应器的转化率大6倍，并且保持了100％的电流效率，可将反式1,2-二溴环己烷[DBCH]催化转化为环己烯。

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《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.17-20|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Abhay Vaze; James F. Rusling;
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Department of Chemistry, Box U-60, 55 North Eagleville Road., University of Connecticut, Storrs, CT 06269-3060;

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正文语种 eng
中图分类化学;
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OPTIMIZING TURNOVER OF A METALLOPOLYION-COATED ELECTRODE IN A FLOW CELL IN MICROEMULSIONS

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