ELECTROREDUCTION OF METHYL AZINYL KETOXIMES AND THEIR Ni(Ⅱ), Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES ON MERCURY - CORRELATION WITH THEIR HYDROLYTIC ACTIVITY

机译：甲基叠氮基酮肟及其镍（Ⅱ），铜（Ⅱ）和锌（Ⅱ）配合物的电还原及其与水解活性的关系

获取原文

获取原文并翻译 | 示例

页面导航

摘要
著录项
相似文献
相关主题

摘要

Ketoximes and their metal chelate complexes are both active as catalysts in hydrolysis of esters. Electroreduction of five azinylmethylketoximes Ⅰ-Ⅴ and their Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ) complexes was investigated polarographically and correlated with acidity of hydroxyimino group, nucleophilicity of dissociated oximate anion and with hydrolytic activity towards model substrate (p-nitrophenylacetate). Three different types of reduction of chelates were observed and their influence on the catalytic activity discussed.

机译：酮肟及其金属螯合物均在酯水解中具有催化活性。极谱法研究了五种氮杂基甲基酮肟肟Ⅰ-Ⅴ及其Ni（Ⅱ），Cu（Ⅱ）和Zn（Ⅱ）配合物的电还原，并与羟基亚氨基的酸度，离解的肟酸阴离子的亲核性以及对模型底物的水解活性有关（p-硝基苯乙酸盐）。观察到三种不同类型的螯合物还原，并讨论了它们对催化活性的影响。

著录项

来源
《Fifth International Manuel M.Baizer Symposium in Honor of Professor Jean Michel Saveant at the 201st Meeting of the Electrochemical Society Centennial Meeting May 12-17, 2002 Philadelphia, PA, USA》|2002年|p.142-145|共4页
会议地点 Philadelphia PA(US);Philadelphia PA(US);Philadelphia PA(US)
作者
Jiri Ludvik; Radek Cibulka;
展开▼
作者单位

J. Heyrovsky Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejskova 3, 182 23 Prague 8, Czech Republic;

展开▼
会议组织
原文格式 PDF
正文语种 eng
中图分类化学;
关键词

相似文献

外文文献
中文文献
专利

1. Design, synthesis, characterization and antibacterial and antifungal activity of a new 2-{(E)-[(4-aminophenyl)imino]-methyl}-4,6-dichlorophenol and its complexes with Co(II), Ni(II), Cu(II) and Zn(II): An experimental and DFT study [J] . Bakirdere Emine Gulhan, Fellah Ferdi Mehmet, Canpolat Erdal, Journal of the Serbian Chemical Society . 2016,第5期

机译：新的2-{（E）-[[（4-氨基苯基）亚氨基]-甲基} -4,6-二氯苯酚及其与Co（II），Ni（II）的配合物的设计，合成，表征以及抗菌和抗真菌活性，Cu（II）和Zn（II）：实验和DFT研究
2. Synthesis, characterization, and antimicrobial activity of complexes of Cu(II), Ni(II), Zn(II), Pb(II), Co(II), Mn(II), and U(VI) containing bidentate Schiff base of [S-methyl-3-(4-methoxybenzylidine)dithiocarbazate] [J] . Kudrat-E-Zahan Md., Islam M. S. Russian Journal of General Chemistry . 2015,第4期

机译：Cu（II），Ni（II），Zn（II），Pb（II），Co（II），Mn（II）和U（VI）的双齿Schiff碱配合物的合成，表征和抗菌活性[S-甲基-3-（4-甲氧基苄基）二硫代氨基甲酸酯]
3. Synthesis and Antimicrobial activity of 2-hydroxy-5-methyl-3-nitro acetophenone thiazole Complexes of Co(II), Ni(II), Cu(II) and Zn(II). [J] . S.R.Kelode Asian journal of research in chemistry . 2013,第11期

机译：Co（II），Ni（II），Cu（II）和Zn（II）的2-羟基-5-甲基-3-硝基苯乙酮噻唑配合物的合成和抗菌活性。
4. Electroreduction of methyl azinyl ketoximes and their Ni(II), Cu(II) and Zn(II) complexes on mercury - correlation with their hydrolytic activity [C] . Jiri Ludvik, Radek Cibulka International Manuel M. Baizer Symposium . 2002

机译：与其水解活性的汞相关甲基氯酮酮及其Ni（II），Cu（II），Cu（II）和Zn（II）复合物的电轭。
5. Effect Assessment of Binary Metal Mixtures of Ni, Cu, Zn, and Cd to Daphnia magna [D] . Boloori, Tahereh 2019

机译：Ni，Cu，Zn和Cd二元金属混合物对大型水蚤的影响评估
6. Preparation Spectroscopic Characterization Theoretical Investigations and In Vitro Anticancer Activity of Cd(II) Ni(II) Zn(II) and Cu(II) Complexes of 4(3 [O] . Ubale Panchsheela Ashok, Shiva Prasad Kollur, Nishad Anil, 2020

机译：CD（II）Ni（II）Zn（II）和Cu（II）复合物的制备光谱性表征理论研究和体外抗癌活性为4（3
7. Synthesis and characterization of Cu(II), Ni(II) and Zn(II) metal complexes of bidentate NS isomeric Schiff bases derived from S-methyldithiocarbazate (SMDTC): bioactivity of the bidentate NS isomeric Schiff bases, some of their Cu(II), Ni(II) and Zn(II) complexes and the X-ray structure of the bisS-methyl-β-N-(2-furyl-methyl)methylenedithiocarbazatozinc(II) complex [O] . M.T.H Tarafder, Kar-Beng Chew, Karen A Crouse, 2002

机译：S-MethythiThiocarbazate（SMDTC）的二齿NS异构席基碱的Cu（II），Ni（II），Ni（II），Ni（II）和Zn（II）金属络合物的合成及表征：二齿NS异构席夫群的生物活性，其中一些Cu（II）），Ni（II）和Zn（II）复合物和双BIS的X射线结构S-甲基-β-N-（2-呋喃基 - 甲基）甲基二硫代氨基甲苯锌（II）复合物
8. Elastic and Inelastic Scattering of 11.0-Mev Protons from 48TI, 51V, 52CR, 54FE, 56FE, 59CO, 60NI, 62NI, 64NI, 63CU, 65CU, 64ZN, 66ZN, and 68ZN: Tabulated Differential Cross Sections. [R] . Dickens, J. K., Perey, F. G., Silva, R. J. 1967

机译：来自48TI，51V，52CR，54FE，56FE，59CO，60NI，62NI，64NI，63CU，65CU，64ZN，66ZN和68ZN的11.0-mev质子的弹性和非弹性散射：列表的差分截面。

ELECTROREDUCTION OF METHYL AZINYL KETOXIMES AND THEIR Ni(Ⅱ), Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES ON MERCURY - CORRELATION WITH THEIR HYDROLYTIC ACTIVITY

摘要

著录项

相似文献

相关主题

期刊订阅