• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文会议>First international symposium on bioanalytical chemistry >THE STUDY ON THE ELECTROCATALYSIS OF NILE BLUE A MODIFIED CARBON FIBER MICROCYLINDER ELECTRODE TO HEMOGLOBIN
【24h】

THE STUDY ON THE ELECTROCATALYSIS OF NILE BLUE A MODIFIED CARBON FIBER MICROCYLINDER ELECTRODE TO HEMOGLOBIN

机译：改性碳纤维微柱电极对血红蛋白的电催化研究。

获取原文
获取原文并翻译 | 示例
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

Recently, The electrodes modified with a lot of dyes as mediators or promoters for the determination of biomolecules and the study of electron transfer process in re.dox of biomolecules have attracted considerable atten-tion[l,2]. However, up to now very little study at a microelectrode has been reported because of its high mass transport rate which makes the catalytic efficiency of homogeneous or heterogeneous reactions decline greatly[3,4]. In the work, the surface of carbon fiber microelectrode was electrochemically oxidized, the process formed many negative charge functional groups. By the interaction between dye with positive charge and surface group, the nile blue A modified microelectrode was fabricated. Although the properties of nile blue A modified glassy carbon and silver electrodes have been studied, and the modified electrodes can catalyze the oxidation of NADH, to our knowledge, there has been no report of nile blue A modified carbon fiber microcylinder electrode and the electrocatalysis of nile blue A to the reduction of hemoglobin. The modified electrode in the work showed significant electrocatalytic activity for the reduction of hemoglobin in week acid media.
机译：近来，用许多染料修饰的电极作为介体或促进剂用于测定生物分子以及研究生物分子氧化还原过程中的电子转移过程已引起人们的广泛关注[1,2]。然而，由于其高的传质速率，使得均相或非均相反应的催化效率大大降低[3,4]，到目前为止，在微电极上的研究还很少。在工作中，碳纤维微电极的表面被电化学氧化，该过程形成了许多负电荷官能团。通过带正电荷的染料与表面基团的相互作用，制备了尼罗蓝A修饰的微电极。尽管已经研究了尼罗蓝A修饰的玻碳和银电极的性能，并且该修饰电极可以催化NADH的氧化，但据我们所知，尚无关于尼罗蓝A修饰的碳纤维微圆柱体电极和对NDH的电催化的报道。尼罗河蓝A能减少血红蛋白。这项工作中的修饰电极对减少周酸性介质中的血红蛋白显示出显着的电催化活性。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号