STRUCTURE AND PROPERTIES OF OXYNITRIDE GLASSES

机译：氧化硝玻璃的结构和性能

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Structure and chemical bonds involving nitrogen in oxynitride glasses have been discussed based on the results of neutron diffraction, NMR spectroscopy and molecular orbital calculation. It has been shown that nitrogen atoms bonded with three silicon atoms exist in oxynitride glasses. It has also been shown that the bending optential of Si-N(Si)-Si angle very sharply rises with inccreasing angle, indicating that the bending is very difficult. It has been discussed that this is the reason for the marked increase in elastic moduli on incorporation of nitrogen in silicate and other oxide glasses.

机译：基于中子衍射，核磁共振谱和分子轨道计算的结果，讨论了氮氧化物玻璃中涉及氮的结构和化学键。已经表明在氧氮化物玻璃中存在与三个硅原子键合的氮原子。还已经表明，Si-N（Si）-Si角的弯曲光学势随着角的增加而急剧增加，这表明弯曲是非常困难的。已经讨论了这是在硅酸盐和其他氧化物玻璃中掺入氮时弹性模量显着增加的原因。

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来源
《Formation, structure and properties of glasses》|1994年|71-80|共10页
会议地点 Beijing(CN)
作者
S.SAKKA;
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作者单位

Institute for Chemical Research, Emeritus of Kyoto University 2-7-30 Kuzuha-Asahi, Hirakata City, Osaka-Fu 573, JAPAN;

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原文格式 PDF
正文语种 eng
中图分类玻璃工业;
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2. Bioactive oxynitride glasses: Synthesis, structure and properties [J] . Bachar Ahmed, Mercier Cyrille, Tricoteaux Arnaud, Journal of the European Ceramic Society . 2016,第12期

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3. Bioactive oxynitride glasses: Synthesis, structure and properties [J] . Bachar Ahmed, Mercier Cyrille, Tricoteaux Arnaud, Journal of the European Ceramic Society . 2016,第12期

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4. STRUCTURE AND PROPERTIES OF OXYNITRIDE GLASSES [C] . China-Japan-Russia trilateral seminar on glassess . 1994

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5. Studies on the Structure and Properties of Oxynitride Glasses [D] . Unuma, Hidero 1993

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6. Crystal and Electronic Structures Photoluminescence Properties of Eu2+-Doped Novel Oxynitride Ba4Si6O16-3x/2Nx [O] . Yuanqiang Li, Yuan Fang, Naoto Hirosaki, 2010

机译：Eu2 +掺杂新型氮氧化物Ba4Si6O16-3x / 2Nx的晶体和电子结构光致发光性能
7. Crystallization pathways and some properties of lithium disilicate oxynitride glasses [O] . Singh, S.P., Rodrigues, A.M., Orsolini, H.D., 2017

机译：二硅氧氮化锂玻璃的结晶途径和某些性能
8. Preparation and Characterization of Properties of Oxynitride Glasses and Fibers. [R] . Gleisner, R. P., DiGuiseppe, T. G. 1989

机译：氮氧化物玻璃和纤维性能的制备与表征。

STRUCTURE AND PROPERTIES OF OXYNITRIDE GLASSES

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